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65 results about "Ferric oxyhydroxide" patented technology

Method for treating complexed chemical nickel electroplating wastewater

The invention provides a method for treating complexed chemical nickel electroplating wastewater and aims at the problem in the existing complexed chemical nickel electroplating wastewater treatment processes that the nickel ion removal efficiency is inadequate. The method comprises the main processes of firstly adding calcium hydroxide into the wastewater, adjusting the pH to 8-9 so as to form calcium phosphate precipitates, adding sulfuric acid into a supernatant liquid so as to adjust the pH of the liquid to 4-5, then, adding a potassium ferrate liquid with strong oxidizing power so as to decomplex in a strong oxidizing manner and change complexed nickel ions into free-state nickel ions, then, adding calcium hydroxide, adjusting the pH to 10-11 so as to enable the free-state nickel ions to form precipitates to be removed from the wastewater, enabling trivalent ferric ions with excellent flocculation function generated after oxidation of ferric acid radical ions to have flocculation with hydroxide precipitates with an adsorption effect, and finally, adding polyacrylamide (PAM) to coagulate and precipitate, thereby removing nickel ions from the electroplating wastewater. The method has the advantages that the condition that the nickel ions obtained after the complexed chemical nickel electroplating wastewater is treated reach the national standards can be effectively guaranteed, the treatment efficiency is high, and the requirements on emission are met.
Owner:陈瀚翔

Fire retardant compositions with reduced aluminum corrosivity

Corrosion-inhibited fire retardant compositions and methods of making and using the same are provided. The corrosion-inhibited fire retardant compositions are comprised of at least one fire retardant component, at least one biopolymer having a particle size diameter of less than about 100 microns, and a corrosion inhibiting system. The corrosion inhibiting system is comprised of at least one corrosion inhibiting compound selected from a group of compounds including azoles, insoluble ferric pyrophosphate, soluble ferric pyrophosphate, ferrous oxalate, ferric citrate, ferrous sulfate, ferric ammonium citrate, soluble ferric orthophosphate, insoluble ferric orthophosphate, ferric ammonium oxalate, ferric ammonium sulfate, ferric bromide, ferric sodium oxalate, ferric stearate, ferric sulfate, ferrous acetate, ferrous ammonium sulfate, ferrous bromide, ferrous gluconate, ferrous iodide, ferric acetate, ferric fluoroborate, ferric hydroxide, ferric oleate, ferrous fumarate, ferrous oxide, ferric lactate, ferric resinate and any combination thereof. In a specific embodiment, the corrosion-inhibited fire retardant composition includes a xanthan biopolymer.
Owner:PERIMETER SOLUTIONS LP

Chemical process

This invention provides a process for preparing sodium ferric gluconate complex in sucrose using the following steps: a) combining a ferric salt solution with a weak alkali chosen from the group consisting of alkaline earth metal and ammonium salts, such as sodium carbonate, sodium bicarbonate, lithium carbonate, potassium carbonate, potassium bicarbonate, ammonium carbonate, ammonium bicarbonate and mixtures thereof, to form the ferric oxyhydroxide; b) combining ferric oxyhydroxide and sodium gluconate in solution to yield the sodium ferric gluconate complex; c) isolating the sodium ferric gluconate complex; and d) combining the sodium ferric gluconate with sucrose in solution to yield the desired sodium ferric gluconate complex in sucrose.
Owner:GENEVA PHARMA INC

Process for production of iron oxyhydroxide particles

The process for production of iron oxyhydroxide particles according to the invention is characterized by comprising a step (A) in which a suspension containing iron(II) is prepared, and a step (B) in which fine bubbles with diameters of 0.05-500 μm are generated in the suspension to form a reaction mixture, and the iron(II) in the reaction mixture is oxidized by the bubbles to produce iron oxyhydroxide particles.
Owner:TDK CORPARATION

Preparation method and application of zero-valent iron/graphene 3D nano-microcapsules

The invention provides a preparation method of zero-valent iron/graphene 3D nano-microcapsules; the preparation method comprises the steps: firstly, respectively oxidating a graphite powder to obtain graphene oxide, and carrying out a hydrolysis reaction of a trivalent iron salt to obtain ferric oxyhydroxide; then treating graphene oxide and ferric oxyhydroxide by an aerosol method to obtain iron oxide/graphene 3D nano-microcapsules; and finally, carrying out high-temperature calcination on the iron oxide/graphene 3D nano-microcapsules in a hydrogen/argon environment to obtain the zero-valent iron/graphene 3D nano-microcapsules. Iron nanoparticles in the iron oxide/graphene 3D nano-microcapsules prepared by the method provided by the invention have good dispersity, are controllable in structure and size, can be stored for a long term and remain stable, and effectively avoid the defects that iron nanomaterials, especially nano zero-valent iron particles, are extremely unstable and are easily passivated and agglomerated. The zero-valent iron/graphene 3D nano-microcapsules prepared by the method can be used in the fields of dye decolorization, heavy metal adsorption and other pollution environmental remediation, as well as magnetic resonance imaging and other magnetic materials.
Owner:CHONGQING TECH & BUSINESS UNIV +1

Preparation of electrochemical sensor with real-time visual colorimetric display

The invention discloses a preparation of an electrochemical sensor with real-time visual colorimetric display, and relates to the technical field of the electrochemical detection. The preparation method comprises the following steps: preparing nickel through a potential deposition method; taking ferric oxyhydroxide/bismuth vanadate nanometer composite material as photoanode, taking electrically-polymerized Prussian blue as photocathode and preparing a laccase catalyst as the biological cathode, and connecting with a portable digital multimeter and a capacitor by utilizing an external coil. Under the specific binding effect of the antigen-antibody, the glucose is promoted to produce hydrogen peroxide under the catalysis of the glucose oxidase, thereby accelerating the nickel under the illumination; in the process of producing the ferric oxyhydroxide/bismuth vanadate photoelectron, the produced instantaneous current can be read through the digital multimeter, and the Prussian blue receiving electron is changed as the Prussian white and can be used as the synchronous colorimetric display. After the reaction is finished, the Prussian white connects with the laccase to recover an initial state and change as the Prussian blue; the circulation of the photocathode material provides great convenience for the construction of the sensor.
Owner:UNIV OF JINAN

Ferric oxyhydroxide material modified by metal-doped cyclodextrin and one-step synthesis method of ferric oxyhydroxide material

The invention relates to a ferric oxyhydroxide material modified by metal-doped cyclodextrin. The ferric oxyhydroxide material is a composite material formed by coating ferric oxyhydroxide and a metalion or metal with cyclodextrin, wherein the mass ratio of the cyclodextrin to the metal ion or metal to the ferric oxyhydroxide is 5-30: 0.1-10: 100; the ferric oxyhydroxide material is prepared by adding iron salt, metal salt and cyclodextrin to water and performing one-step reaction synthesis. The composite material provided by the invention greatly improves a catalysis effect of the ferric oxyhydroxide by doping of precious metals or transition metals and modification of cyclodextrin, not only has characteristics of hydrogen peroxide catalysis, photocatalysis, enzyme-like catalysis and thelike, but also has a host-guest inclusion effect of cyclodextrin supermolecules, and plays an important role in catalytic degradation of pesticide, physiological hormone and other types of pollutantsin water by the excellent catalysis performance and the inclusion effect of supermolecules.
Owner:SHANDONG UNIV

Method for removing organic matters in reclaimed water by using in situ FeOxHy

The invention relates to the field of treatment of reclaimed water, especially to a method for removing organic matters in reclaimed water by using in situ FeOxHy. Directed at the problem that secondary effluent of a municipal sewage plant has high content of organic matters, the invention brings forward the method of improving removal effects of coagulation, deposition and filtration units of a reclaimed water plant on organic matters by using combined action of an alkali salt and a ferric salt, wherein an alkali salt solution and a ferric salt solution are added according to a certain mol ratio and react with each other to produce in situ FeOxHy which enables organic matters in water to be agglomerated and adsorbed and settling properties of floc to be improved, and removal of the organic matters is further realized by using a solid-liquid separation reactor. The method can be used for deep purification of secondary effluent of the municipal sewage plant and is also applicable to a reclaimed water treatment project using effluent of the municipal sewage plant or rainwater as a water source.
Owner:BEIJING UNIVERSITY OF CIVIL ENGINEERING AND ARCHITECTURE

Visible-light-driven self-cleaning graphene oxide oil-water separation membrane as well as preparation method and application thereof

ActiveCN111871225AImprove hydrophilicityGood underwater superoleophobic wetting propertiesSemi-permeable membranesMembranesFerric oxyhydroxideMembrane surface
The invention provides a preparation method of a visible-light-driven self-cleaning graphene oxide oil-water separation membrane. The preparation method comprises the following steps: S1, preparing aGO / TA composite membrane; and S2, loading iron oxyhydroxide on the GO / TA composite film prepared in the step S1 to prepare a GO / TA@FeOOH-x composite film. According to the preparation method of the visible-light-driven self-cleaning graphene oxide oil-water separation membrane provided by the invention, a stable ultrathin skin layer with a good oil-water separation effect is constructed on the surface of a PVDF membrane by utilizing the good film-forming property of the two-dimensional material graphene oxide, so that a stable graphene oxide oil-water separation membrane is formed; further, through a mineralization reaction of ferric ions in a ferric trichloride solution, ferric oxyhydroxide particles are loaded on a tannic acid modified graphene oxide sheet layer, therefore, the preparedvisible-light-driven self-cleaning graphene oxide oil-water separation membrane has good hydrophilic performance and underwater super-oleophobic wetting performance and also has excellent visible-light-driven self-cleaning capability.
Owner:XIHUA UNIV +1

Activated carbon supporting ferric oxyhydroxide composite adsorbent, and preparation and application thereof

The invention belongs to the technical field of water body purification, and discloses an activated carbon supporting ferric oxyhydroxide composite adsorbent, and preparation and application thereof.A preparation method includes the steps of: 1) acidifying the activated carbon, changing water to boil the activated carbon, washing the activated carbon, and changing water to boil the activated carbon, repeating the operations hereinabove until a filtrate is clear and transparent after the activated carbon is washed, and drying the activated carbon and calcining the activated carbon at high temperature to prepare pretreated activated carbon; 2) uniformly dispersing the pretreated activated carbon in a FeCl3 solution, sealing the mixture, performing an infiltration reaction, and washing and drying the product to prepare the activated carbon supporting ferric oxyhydroxide composite adsorbent. The method is simple and low-cost. In the composite adsorbent, the ferric oxyhydroxide is in a spindle-like shape and is uniformly supported on the activated carbon. The composite adsorbent is stable and can remove bromates in water high-effectively, is easy to recycle, and is used for removing the bromates in drinking water.
Owner:SOUTH CHINA UNIV OF TECH

Method for degrading guanidine gum in waste fracturing fluid under coupling of potassium ferrate and ultrasonic intensification

The invention relates to the technical field of waste fracturing fluid, in particular to a method for degrading guanidine gum in waste fracturing fluid under the coupling of potassium ferrate and ultrasonic intensification. The method includes the following steps that firstly, the waste fracturing fluid is separated after standing to obtain clear fluid; secondly, absolute ethyl alcohol is added into the clear fluid for purification; thirdly, an alkali regulator is added into the purified guanidine gum solution to regulate the pH value; fourthly, a potassium ferrate aqueous solution is added, meanwhile external-field ultrasonic intensification and oxidization are carried out, and qualified flowback fracturing fluid is obtained. According to the method of deeply oxidizing guanidine gum in the waste fracturing fluid with potassium ferrate under external-field ultrasonic intensification, guanidine gum is deeply oxidized under the coupling of the oxidizing agent and the external-field acting force, and the CODCr value and viscosity of the waste fracturing fluid are effectively reduced; meanwhile, secondary pollution is not generated in the treating process as potassium ferrate serves as the oxidizing agent and is environmentally friendly, and the chroma of the flowback fluid is increased as ferric hydroxide generated after potassium ferrate is reduced has the flocculation and precipitation effect.
Owner:BC P INC CHINA NAT PETROLEUM CORP +1

Method for inhibiting carbon dioxide released by mineralizing organic material

InactiveCN101407437AReduce the degradation rateInhibit mineralization releaseFerric hydroxideSludge
The invention relates to a method for inhibiting the release of carbon dioxide caused by the mineralization of organic materials, which belongs to the technical field of resource reuse and comprises the following steps: (1) organic materials are collected, which mainly comprise sludge, pig manure or paddy straw; (2) the organic materials are respectively dried and crashed into 60-mesh powder; (3) according to the proportion that 5ml of 0.2mol / L ferric hydroxide colloid is added to every 10g of dried organic materials, granulation is carried out; and (4) at room temperature, the granules are aired and aged for about 8-15 days to prepare the dry granular products of the sludge, the pig manure or the paddy straw. The method has the advantages of simple operation and low cost; the product prepared by the method can effectively reduce the degradation rate of the organic materials, thus being beneficial for climatic environment protection. The method can be further popularized as a way of large-scale treatment of the organic materials, and the product can be used both as an effective organic material and a soil improvement agent, thereby achieving the effect of killing two birds with one stone.
Owner:NANJING AGRICULTURAL UNIVERSITY

Wet treatment method for ferronickel and application thereof

The invention discloses a wet treatment method for ferronickel and application thereof; and the treatment method comprises the following steps of: in a high-pressure oxygen environment, mixing crushed ferronickel, sulphuric acid and a corrosion aid, performing acid leaching reaction, performing solid-liquid separation on slurry after acid leaching, adding an oxidizing agent into the obtained filtrate, performing heating, removing the corrosion aid, adding a precipitator into the filtrate, controlling the pH value of the filtrate, and performing solid-liquid separation to obtain ferric hydroxide precipitate and nickel-containing filtrate; and performing extraction and back extraction on the nickel-containing filtrate to prepare battery-grade nickel sulphate. According to the invention, the ferronickel is subjected to oxidation acid dissolution in cooperation with the corrosion aid under the high-pressure oxygen and acidic conditions; the ferronickel is extremely prone to oxidation in the high-pressure oxygen environment; and a strong oxidant is added into the filtrate subsequently, so that ferrous ions in the filtrate are completely converted into ferric ions, the corrosion aid can be oxidized to generate pollution-free carbon dioxide and water, and the influence of the corrosion aid on the subsequent extraction process is avoided.
Owner:GUANGDONG BRUNP RECYCLING TECH +2

Filter media for removing methyl tert-butyl ether in water and preparation method thereof

The invention discloses filter media for removing methyl tert-butyl ether in water, a preparation method thereof and a filter core prepared by the filter media. The preparation method provided by the invention comprises the following steps of: displacing a mixture into a mould pressing machine for mould pressing, sintering at the temperature of 150-250 DEG C for 30-100 minutes, cooling and demoulding to obtain the filter media, wherein the mixture contains, by weight, 250-500 parts of ultrahigh molecular weight polyethylene, 300-500 parts of phenol-absorbed wood-based activated carbon, 10-50 parts of a gas generation agent, and 200-350 parts of limestone particles with ferric oxyhydroxide coated on the surface. The ultrahigh molecular weight polyethylene, the phenol-adsorbed wood-based activated carbon and the limestone particles with ferric oxyhydroxide coated on the surface all have a strong adsorption to methyl tert-butyl ether. Therefore, by the cooperation of the above raw materials, the filter core prepared by the filter media can effectively remove methyl tert-butyl ether in water to be processed.
Owner:QIDI ELECTRIC GROUP

Efficient water quality purification composite material

The invention discloses an efficient water quality purification composite material which is prepared from the following raw materials in parts by weight: 6-10 parts of soybean protein, 8-14 parts of hollow glass micro-beads, 5-9 parts of kaolin, 6-8 parts of calcium sulfate, 1-5 parts of aloe, 5-9 parts of hydroxyl-terminated polyester cyclo-polyhydric alcohol, 2-6 parts of a cement mortar solution, 7-11 parts of toluene diisocynate, 2-5 parts of ferric hydroxide, 1-3 parts of an antioxidant, 2-7 parts of ion exchange resin, 2-6 parts of hydroxyapatite and 2-4 parts of gypsum powder. The efficient water quality purification composite material disclosed by the invention has the beneficial effects that the efficient water quality purification composite material can be used for better adsorbing pollutants suspending in water and improving precipitation; meanwhile, the efficient water quality purification composite material is free from secondary pollution, and is simple and safe.
Owner:QINGDAO CHANGANDA PHARMA IND CO LTD

Method for preparing mesoporous Alpha-Fe2O3/Alpha-Al2O3 and magnetic mesoporous Gamma-Fe2O3/Alpha-Al2O3 nanoscale composite materials under low-temperature condition

The invention discloses a method for preparing mesoporous Alpha-Fe2O3 / Alpha-Al2O3 and magnetic mesoporous Gamma-Fe2O3 / Alpha-Al2O3 nanoscale composite materials under a low-temperature condition. By a soluble aluminium salt and ferric salt hydrolysis method, aluminium hydroxide and ferric hydroxide sol are prepared, and the sol is then dried to remove free water, so that corresponding aluminium hydroxide and ferric hydroxide xerogel is obtained; moisture in molecules is lost by calcination, so that the mesoporous Alpha-Fe2O3 / Alpha-Al2O3 nanoscale composite material is obtained, and then by reduction, the magnetic mesoporous Gamma-Fe2O3 / Alpha-Al2O3 nanoscale composite material is obtained. The grain size of the nanoscale Alpha-Al2O3 particles prepared by the method under 800 DEG C is about 50nm, and as an initial material for the preparation of alumina ceramic and a doping component for the preparation of composite materials and coating materials, the mesoporous Alpha-Fe2O3 / Alpha-Al2O3 and magnetic mesoporous Gamma-Fe2O3 / Alpha-Al2O3 nanoscale composite materials are of great significance.
Owner:SHANGHAI UNIV

Preparation method of iron-based composite catalyst for catalytic ozonation treatment of coal chemical wastewater

The invention discloses a preparation method of an iron-based composite catalyst for catalytic ozonation treatment of coal chemical wastewater. The preparation method comprises the following steps: activating / pretreating a carrier, preparing a metal precursor solution, loading Fe onto an Al2O3 carrier, and performing oscillating, aging, drying and washing. According to the preparation method, the aluminum oxide is taken as the carrier, urea is taken as a self-sacrifice template, so that iron oxide is loaded on the surface of aluminum oxide, and the existence of urea is beneficial to precipitation of iron on the carrier; when heating is carried out at 90-120 DEG C, urea can be decomposed very slowly to form hydroxyl groups, and the hydroxyl groups are uniformly distributed on the surface and pores of the Al2O3 carrier; then, ferric hydroxide and ferric oxyhydroxide are precipitated on the surface of the carrier. The active substance directly grows on the surface of the carrier, so that the stability and dispersity of Fe are obviously improved, and meanwhile, the loading amount of Fe on the carrier is increased.
Owner:CCTEG CHINA COAL RES INST +1

Method for preparing three-dimensional graphene by using polybenzimidazole (PBI) macromolecules

The invention provides a method for preparing three-dimensional graphene. mPBI in polybenzimidazole (PBI) serve as carbon and nitrogen sources, nano silica, iron oxide, ferric hydroxide and magnesium oxide particles serve as template agents, the surfaces of nano particles are uniformly coated with PBI after dissolution, benzimidazole rings in macromolecules are regularly arranged on the surfaces of the template agents, the template agents are removed through pyrolysis, the nitrogen doped three-dimensional graphene is obtained, and multistage thorough pore passages can strengthen mass transfer. The requirements are that the viscosity average molecular weight of the mPB is 30-50 thousand; the particle size of the template agents is 5-50 nm; the mass ratio of the mPB to the template agents is 3:1 to 1:3; pyrolysis temperature is 800-1100 DEG C; the pyrolysis time is 2-3 hours, washing is performed with diluted hydrochloric acid (or hydrofluoric acid) for three times, and washing is performed with deionized water for three times. The prepared three-dimensional graphene is used for oxidation-reduction reaction catalysts and oxygen precipitation catalysts and used in the fields such as fuel cells, metal air batteries and electrolysis, and can be also used in the fields such as supercapacitors, lithium ion batteries and sensors.
Owner:SHANDONG UNIV OF TECH
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