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51results about How to "Yield loss" patented technology

Hydrocyanation process with reduced yield losses

ActiveUS20080015381A1Investment exemptionSelective and efficient and stableOrganic compound preparationPreparation by hydrogen cyanide additionNitriteHydrogen
The invention provides a hydrocyanation process for the production of adiponitrile and other dinitriles having six carbon atoms, the process comprising:
    • a) forming a reaction mixture in the presence of at least one Lewis acid, said reaction mixture comprising ethylenically unsaturated nitrites having five carbon atoms, hydrogen cyanide, and a catalyst precursor composition, by continuously feeding ethylenically unsaturated nitrites, hydrogen cyanide, and a catalyst precursor composition;
    • b) controlling X and Z, wherein X is the overall feed molar ratio of 2-pentenenitriles to all unsaturated nitriles and Z is the overall feed molar ratio of hydrogen cyanide to all unsaturated nitrites, by selecting a value for X in the range from about 0.001 to about 0.5, and a value for Z in the range from about 0.5/1 to about 0.99/1, such that the value of quotient Q, wherein
Q=X[(moles3PN+4PNinthefeed)(molesallunsaturatednitrilesinthefeed)]-Z
is in the range from about 0.2 to about 10, wherein 3PN is 3-pentenenitriles and 4PN is 4-pentenenitrile; and
    • c) withdrawing a reaction product mixture comprising adiponitrile;
    • wherein the ratio of the concentration of 2-pentenenitriles to the concentration of 3-pentenenitriles in the reaction mixture is from about 0.2/1 to about 10/1;
    • wherein the catalyst precursor composition comprises a zero-valent nickel and at least one bidentate phosphite ligand; and
wherein the bidentate phosphite ligand is selected from a member of the group represented by Formulas I and 11 as described herein.
Owner:INV NYLON CHEM AMERICAS LLC

Hydrocyanation process with reduced yield losses

ActiveUS20080015382A1Investment exemptionSelective and efficient and stableOrganic compound preparationPreparation by hydrogen cyanide additionHydrogenPhosphite ester
The invention provides a hydrocyanation process for the production of adiponitrile and other dinitriles having six carbon atoms, the process comprising:
    • a) forming a reaction mixture in the presence of at least one Lewis acid, said reaction mixture comprising ethylenically unsaturated nitriles having five carbon atoms, hydrogen cyanide, and a catalyst precursor composition, by continuously feeding ethylenically unsaturated nitriles, hydrogen cyanide, and a catalyst precursor composition;
    • b) controlling X and Z, wherein X is the overall feed molar ratio of 2-pentenenitriles to all unsaturated nitriles and Z is the overall feed molar ratio of hydrogen cyanide to all unsaturated nitriles, by selecting a value for X in the range from about 0.001 to about 0.5, and a value for Z in the range from about 0.5/1 to about 0.99/1, such that the value of quotient Q, wherein
Q=X[(moles3PN+4PNinthefeed)/(molesallunsaturatednitrilesinthefeed)]-Z
is in the range from about 0.2 to about 10, wherein 3PN is 3-pentenenitriles and 4PN is 4-pentenenitrile; and
    • c) withdrawing a reaction product mixture comprising adiponitrile;
    • wherein the ratio of the concentration of 2-pentenenitriles to the concentration of 3-pentenenitriles in the reaction mixture is from about 0.2/1 to about 10/1;
    • wherein the catalyst precursor composition comprises a zero-valent nickel and at least one multidentate phosphorus-containing ligand;
    • wherein the multidentate phosphorus-containing ligand is selected from the group consisting of a phosphite, a phosphonite, a phosphinite, a phosphine, and a mixed phosphorus-containing ligand or a combination of such members; and
    • wherein the multidentate phosphorus-containing ligand gives acceptable results according to at least one protocol of the 2-Pentenenitrile Hydrocyanation Test Method.
Owner:INV NYLON CHEM AMERICAS LLC

Moving bed process for producing propylene, recycling a fraction of used catalyst

The invention concerns a process for producing propylene from a steam cracking and / or catalytic cracking light olefinic cut, said process comprising a moving bed catalytic cracking step with a catalyst regeneration loop. The process recycles a portion of the used catalyst to the inlet of the moving bed reactor. The conversion is high using the process of the invention, with a good yield and good propylene selectivity.
Owner:INST FR DU PETROLE

Gelatin Production System

Process for the preparation of gelatin from fish parts includes the steps of washing the fish parts with an aqueous solution of a calcium hydroxide hydrate and ice to remove blood from the fish parts, treating the washed skins with an acid, and extracting gelatin from the fish skins at a temperature approximately between 100 Fahrenheit to 170 Fahrenheit and at an acidic pH approximately between pH 1.5 to pH 5.5.
Owner:BERNEGGER PETER M +1

Method for optimizing the yield of a partially shaded photovoltaic array

A method for optimizing the yield of a photovoltaic array with an inverter is provided. The method includes: a) cyclically measuring a current (Igiv) and a DC link voltage (U) when controlling the inverter by a MPP method (Maximum Power Point) and storing a measured current value, b) lowering the DC link voltage (U) to a value that exceeds by no more than 100% a minimum DC link voltage (Umin) admissible for operation of the inverter, c) measuring a current (Ired) with a reduced DC link voltage and comparing it with a previously stored value at a given time for the current (Igiv), d) if a prescribed threshold for a difference between the two currents (Ired, Igiv) is exceeded, a searching process for a global MPP (Maximum Power Point) is initiated, e) otherwise, operation is continued at a power maximum (MPP) with a last-stored current value for the current (Igiv).
Owner:KACO NEW ENERGY GMBH
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