The invention discloses a flexible transparent
piezoelectric composite film, a transparent stretchable ultrasonic
transducer and a preparation method thereof. The flexible composite transparent film is mainly obtained by constructing a chemical
heterojunction and designing the structure of each phase ferroelectric domain wall in the composite piezoelectric film. According to the method, firstly, a chemical
heterojunction is formed in a
composite film precursor solution through an in-situ synthesis method, the chemical
heterojunction can improve
voltage distribution of an inorganic piezoelectric phase dispersion unit in the
composite film when the inorganic piezoelectric phase dispersion unit is polarized, and
dipole moment orientation under the action of an
electric field is remarkably improved; and then, applying an alternating
electric field to the formed non-transparent flexible
composite film for polarization, so continuous ferroelectric domains are fused with each other, and the number of the ferroelectric domains is reduced. And finally, the flexible composite piezoelectric film with high transparency, high piezoelectric property and low
acoustic impedance is prepared and is finally applied to a transparent stretchable ultrasonic
transducer, particularly applied to photoacoustic imaging of non-planar tissues such as craniocerebral tissues and the like, the
light transmission efficiency in photoacoustic imaging is improved, and the
imaging quality is improved.