The invention relates to a luminous warning road reflective paint and a construction method thereof. The coating is composed of a primer and a topcoat; by weight percentage, the A component of the primer includes: two-component room temperature curing acrylic resin, luminous powder, leveling agent, wetting and dispersing agent, the first defoamer, catalyst Drying agent, toner, reactive diluent, primer B component includes: initiator, reactive diluent; topcoat A component includes: two-component room temperature curing fluorocarbon resin, glass beads, anti-settling agent, second 2. Defoamer, drier, solvent; topcoat component B includes: curing agent, thinner. The coating formed by the coating of the present invention has a good surface state, is not easily polluted, has good reflection effect, strong adhesion, and the marking line is not easily deformed, and has good stability at the same time, which is beneficial to reducing the later maintenance cost.