The invention discloses front silver paste for a crystalline silicon solar cell, and a preparation method and application thereof. The front silver paste for crystalline silicon solar cell includes anorganic carrier, an organic auxiliary agent, glass powder and silver powder, wherein the raw material of the glass powder comprises TeO2, an adhesion additive, Bi2O3, MgO, Ag2O and ZnO, and optionally includes one or more of Al2O3, ZrO2, R2O, PtO2 and MoO; the adhesion additive is one or more selected from oxides of Si, P, B or Ge; and R2O is one or more selected from oxides or salts of Li, Na orK. The preparation method of the front silver paste for a crystalline silicon solar cell includes the steps: weighing each component according to the formula, mixing the components, grinding the mixture until the particle size of the paste is less than 5 mu m, and controlling the viscosity of the paste, thus completing preparation. The invention also relates to an application for preparation of the passivation crystalline silicon solar cell. The front silver paste for a crystalline silicon solar cell can realize high welding adhesion between a front silver electrode and a welding strip whilemaximizing the electrical performance of the solar cell, and the cell pack has a long service life.