The invention discloses a method for preparing high-purity low-
chlorine electroplating-grade cupric
oxide. According to the method,
copper,
liquid ammonia and high-purity
carbon dioxide are taken as raw materials, stronger
ammonia water is prepared firstly, carbonated
ammonia water is obtained through introducing the high-purity
carbon dioxide into the stronger
ammonia water and controlling
carbonization degree, the carbonated ammonia water reacts with the
copper under certain air pressure so as to prepare
copper-ammonia complexation liquid, the copper-ammonia complexation liquid is then subjected to heating, ammonia distilling, separating, washing,
drying and sieving so as to prepare high-purity heavy
basic copper carbonate, and the heavy
basic copper carbonate is then subjected to heating
calcination and
decomposition, thereby preparing the high-purity low-
chlorine electroplating-grade cupric
oxide. According to the method, the
carbon dioxide is directly used as a
raw material, so that the problems of the traditional method that impurities, such as heavy
metal ions and
chloride ions, are introduced by raw materials used in the production of
basic copper carbonate are solved, the rate of reaction is increased, the
production cycle is shortened, the production efficiency is greatly increased, and products are low in
impurity content, high in purity, high in activity and wider in application; and meanwhile, the method is high in yield, low in
energy consumption, and low in cost and hardly causes
pollution.