The invention relates to a high-heat-conductivity vacuum-tolerant high-temperature-tolerant anticorrosion coating and belongs to the technical field of macromolecular special engineering plastic; the high-heat-conductivity vacuum-tolerant high-temperature-tolerant anticorrosion coating comprises a bottom coating and a surface coating; the bottom coating is prepared from, by applying, by weight, 20-40% of PEKK (polyetherketoneketone) superfine powder, 0-10% of a cosolvent, 1-10% of tackified glue, 0.01-1% of pigment-filler, 0.5-3% of a surfactant, 0.5-3% of a defoaming agent, and 0-2% of a leveling agent; the surface coating is prepared from, by applying, by weight, 86-98.5% of PFA (perfluoroalkoxy alkane) fine powder, 0-10% of PPS (polyphenylene sulfide) micropowder, 1-3% of diamond micropowder, and 0.5-1% of hydrophilic silicon dioxide. The high-heat-conductivity vacuum-tolerant high-temperature-tolerant anticorrosion coating is very suitable for application in the field of high-temperature-tolerant anticorrosion coating requiring heat transfer, particularly high-heat-conductivity high-temperature-tolerant anticorrosion application for thin-walled devices, and has the advantages of high binding force, surface smoothness, and good heat conductivity.