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109 results about "Oxygen precipitation" patented technology

Porous nitrogen-doped carbon supported cobalt nano-material, preparation method and application thereof

The invention relates to a porous nitrogen-doped carbon supported cobalt nano-material, a preparation method and application thereof. The preparation method comprises the steps of dissolving a cobaltsource in a sodium citrate solution, having a hybrid reaction with cobalt potassium cyanide to obtain a Prussian blue similar nanocube; mixing and stirring with a dopamine aqueous solution in a buffering solution to obtain a dopamine coated cobalt-based Prussian blue composite material; after drying, annealing and roasting at a high temperature; then adding inorganic acid in a reaction kettle foracid-pickling to obtain the porous nitrogen-adopted carbon supported cobalt nano-material. The result shows that the material has a relatively good electronic transmission performance, a huge specificsurface area, good stability and many active site, has relatively good electrocatalytic activity in alkaline electrolyte and can serve as a three-function catalyst for oxygen precipitation, hydrogenprecipitation and oxygen reduction reaction.
Owner:SHENZHEN UNIV

High-load precious metal monatomic catalyst as well as preparation method and application of high-load precious metal monatomic catalyst

The invention relates to a high-load precious metal monatomic catalyst as well as a preparation method and application of the high-load precious metal monatomic catalyst. The high-load precious metalmonatomic catalyst is prepared by adsorbing precious metal acid radical ions or salt ions by taking a nitrogen-doped carbon material as a carrier, and then, radiating the obtained precursor powder byusing ultraviolet with a certain strength for a period of time. The catalyst has high active site density and high precious metal utilization ratio and shows excellent performances in reactions such as electrically-catalyzed hydrogen precipitation, oxygen reduction and oxygen precipitation.
Owner:BEIJING UNIV OF CHEM TECH

Transition metal nitride/carbon electrocatalyst and preparation method and application of transition metal nitride/carbon electrocatalyst

The invention relates to electrochemical power sources and the field of electrochemical catalysis, and particularly relates to a transition metal nitride / carbon electrocatalyst. The transition metal nitride / carbon electrocatalyst comprises a substrate and a shell, the substrate is coated by the shell, and the shell comprises copper nitride and further comprises a carbon material or a nitrogen doped carbon material. The invention further provides a preparation method of the electrocatalyst, and the electrocatalyst is prepared by forming MOF of copper in advance, then further aminating and calcining through one step, and preparing the electrocatalyst. The processes of oxygen precipitation and hydrogen precipitation show the low overpotential in the alkaline environment, and the electrocatalyst can be used as a catalyst material of alkaline efficient electrolysed water.
Owner:CENT SOUTH UNIV

Horizontal three-electrode electrochemical rechargeable zinc-air battery

The invention discloses a horizontal three-electrode electrochemical rechargeable zinc-air battery, belonging to the technical field of an electrochemical power supply. The battery comprises an oxygen precipitation electrode, a zinc electrode and a battery module and also comprises an oxygen reduction electrode, wherein the oxygen precipitation electrode, the zinc electrode and the oxygen reduction electrode are all horizontally arranged and assembled together by using the battery module, the zinc electrode and the oxygen precipitation electrode form a working loop during charging, and the zinc electrode and the oxygen reduction electrode form a working loop during discharging. The structure disclosed by the invention is favorable for battery sealing, the gravity effect during the charging and discharging process is eliminated, and zinc dendrite generation and zinc electrode deformation are prevented; by using a three-electrode system, the corrosion of oxygen generated during charging of a two-electrode system to an air electrode and the damage to a physical structure are avoided, and the cycle life of the battery is prolonged; and the horizontally-arranged electrodes are immersed in an electrolyte, thus, an oxygen diffusion channel built on the oxygen precipitation electrode is prevented, the electrode structure is greatly simplified, and the electrode fabrication and amplification is promoted.
Owner:TSINGHUA UNIV

Preparation method for lithium-nickel-cobalt-manganese-vanadium oxygen electrode material

The invention provides a preparation method for a lithium-cobalt-nickel-manganese-vanadium oxygen electrode material, which comprises the following steps of: a-, dissolving soluble salts of lithium, nickel, manganese, cobalt and vanadium into metallic solution formed by water and an organic solvent, evenly mixing the metallic solution with mixed alkali liquor prepared from ammonia water, ammonium carbonate, hydrogen peroxide and polyethylene glycol in proportion; and then, atomizing and heating to form lithium-nickel-cobalt-manganese-vanadium oxygen precipitations; b-, baking and briquetting the lithium-nickel-cobalt-manganese-vanadium oxygen precipitations; calcining under an air atmosphere to obtain a sintered product; cooling, grinding and screening the sintered product; and then calcining under an oxygen atmosphere to form the lithium-cobalt-nickel-manganese-vanadium oxygen material. The preparation provided by the invention is simpler n step, is lower in cost and is milder in high-temperature calcining condition.
Owner:TIANNENG SAFT ENERGY JOINT CO +2

Lead-carbon battery positive electrode lead plaster added with electroconductive glass fiber

The invention discloses a lead-carbon battery positive electrode lead plaster added with electroconductive glass fiber, composed of the following constituents in percentage by weight of lead powder: 0.1-0.4% of stannous sulfate, 0.05-0.3% of antimonous oxide, 0.1-1.0% of electroconductive glass fiber, 0-0.2% of graphite, 8.0-10.0% of sulfuric acid with density of 1.40g / mL, and 10.0-15.0% of deionized water. According to the invention, the electroconductive glass fiber partly or completely replaces graphite material, and is directly mixed with the lead powder, thus, electrical conductivity of positive electrode active substance is improved, oxygen precipitation of the positive electrode can be reduced, utilization rate of the positive electrode active substance is improved, battery service life is prolonged, the lead-carbon battery positive electrode lead plaster is matched with a lead-carbon negative electrode, and integral performance of the lead-carbon battery is improved. The electroconductive glass fiber also can play a role in improvement of binding force strength of the lead plaster, and has no adverse effect on the positive electrode active substance; after the volume of addition is increased, electron conduction distance of the battery in a discharging process is shorter, reaction depth is higher, thus, battery capacity, charging receptivity and rate discharge performance are improved markedly.
Owner:TIANNENG GRP JIANGSU TECH

Nitrogen-doped carbon-coated nickel composite nano-carbon electrolysis water catalyst as well as preparation method thereof

The invention relates to a nitrogen-doped carbon-coated nickel composite nano-carbon electrolysis water catalyst as well as a preparation method thereof. The nitrogen-doped carbon-coated nickel composite nano-carbon electrolysis water catalyst is prepared by the following steps: preparing a single-wall carbon nanotube composite material comprising carbon coated nickel by virtue of a DC arc discharging method, then removing amorphous carbon by virtue of oxidation and acid dissolving, further nitriding at a high temperature in an ammonia atmosphere, and obtaining a nitrogen-doped porous netted single-wall carbon nanotube composite material comprising the carbon coated nickel. The preparation method is low in raw material cost, simple and easy in operation and easy in mass production. The single-wall carbon nanotube composite material obtained in the DC arc discharging method has a porous netted structure, so that the precipitation of oxygen and hydrogen is facilitated, after the amorphous carbon is removed and the electron state on the surface of the carbon is optimized in a nitriding manner, the electrolysis water oxygen precipitation catalytic performance has better catalytic activity than the iridic oxide which is widely used in the industry, and the nitrogen-doped carbon-coated nickel composite nano-carbon electrolysis water catalyst has good catalytic hydrogen production activity when being used as an electrolytic water anode catalyst.
Owner:FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI

Bifunctional catalyst for oxygen evolution and oxygen reduction reaction and preparation method thereof

The invention relates to a bifunctional catalyst for the oxygen evolution and oxygen reduction reaction and a preparation method thereof, and belongs to the technical field of new materials and the preparation thereof. The catalyst is a composite material composed of a nano-carbon material, a porphyrin organic skeleton material and a metal oxide or hydroxide. The preparation method of the catalystis that: the porphyrin organic skeleton material intermediate is prepared by the polymerization reaction of the nano-carbon material, a five-membered heterocycle and a polyaldehyde according to a certain proportion, and then the porphyrin organic skeleton material intermediate is mixed with an aqueous solution of a metal salt and an alkali according to a certain proportion to prepare the catalystby the in-situ precipitation method. The high-performance bifunctional catalyst for the oxygen precipitation and oxygen reduction reaction is provided, and the activity of the non-noble metal bifunctional catalyst is greatly improved. The synthesis method of the catalyst has the advantages of simple operation, low cost and easy amplification, the catalyst is expected to be used as a cathode catalytic material for metal-air batteries and fuel cells, and thus the research and application of clean and sustainable energy devices is promoted.
Owner:TSINGHUA UNIV

Preparation method of transition metal and nitrogen doped multistage pore-passage three-dimensional graphene

The invention provides a preparation method of a transition metal and nitrogen doped multistage pore-passage three-dimensional graphene. Soluble full-aromatic polybenzimidazole (PBI) serving as carbon and nitrogen sources, transition metal salt and a PBI solution react to obtain a PBI and transition metal ion complex, nano calcium carbonate is added in the mixed liquid to serve as a template agent, even mixing and concentration are performed to coat and regularly arrange the complex on the surface of the template agent, the template agent is removed through pyrolysis, the transition metal and nitrogen doped three-dimensional graphene with a multistage pore-passage structure is obtained, and multistage thorough pore passages can strengthen mass transfer. The viscosity average molecular weight of the PBI is 2-40 thousand. The molar ratio of the PBI to the transition metal is 1:2 to 2:1. The template agent is calcium carbonate, and the particle size of the template agent is 30-100 nm. The mass ratio of the PBI to the template agent is 2:1 to 1:4. Pyrolysis temperature is 800-1100 DEG C. The product can be used for oxidation-reduction reaction catalysts, fuel cells, metal air batteries, oxidation-reduction reaction catalysts, electrolytic water oxygen precipitation catalyst, supercapacitors and other fields.
Owner:SHANDONG UNIV OF TECH

Preparation of 3D graphene co-doped with cobalt and nitrogen

The invention relates to a preparation of 3D graphene co-doped with cobalt and nitrogen. The 3D graphene co-doped with cobalt and nitrogen is prepared by regularly arranging complexes formed by soluble all-aromatic PBI (polybenzimidazole) and cobalt salt on template nanoparticle surfaces through pyrolysis, template removal and other process routes. PBI is selected from all-aromatic polymers such as ABPBI, mPBI and the like, and the viscosity average molecular weight ranges from 20,00 to 40,000; the mass ratio of PBI to cobalt salt is 1:2-2:1; the template is nanoparticles such as nano magnesium oxide, iron oxide, ferric hydroxide and the like and has the particle size of 5-50 nm; the mass ratio of PBI to the template is 3:1-1:3; the pyrolysis temperature is 700-1,100 DEG C. The product can be applied to the fields of redox reaction catalysts, fuel cells, metal-air battery redox catalysts, water electrolysis oxygen precipitation catalysts, supercapacitors and the like.
Owner:SHANDONG UNIV OF TECH

Electrolyzed water catalyst of nonconventional local area structure and preparation method thereof

The invention relates to an electrolyzed water catalyst of nonconventional local area structure and a preparation method thereof. In the preparation method, A-position element of perovskite is selectively dissolved by using a method of treatment through an ultrasonic-assisted ferric iron solution, perovskite crystal oxide with small specific surface area is converted into amorphous hydroxide of ananostructure, and the hydroxide has extraordinary local area electron structure and geometric structure, thereby having ultrahigh oxygen precipitation performance. In consideration of pH difference of AB-position elements of a perovskite material, ferric iron with proper acidity is selected as a regulator, material structure is changed, and new active sites are introduced, so that ultrahigh OER activity is caused; the catalyst can be applied in the field of fuel cells, metal-air cells and water electrolysis.
Owner:NANJING UNIV OF TECH

Method for preparing nano Co3O4/carbon nanotube integral air electrode catalysis material

The invention discloses a method for preparing a nano Co3O4 / carbon nanotube integral air electrode catalysis material. The method comprises the following steps: oxidizing the surface of a carbon nanotube to achieve surface functionalization, and combining the carbon nanotube as a carrier with uniform and dense nano Co3O4 particles through chemical bonds by using a thermal treatment method, so as to form an integral air electrode catalysis material which is free of adhesive connection and stable in structure. The integral air electrode catalysis material which is prepared by using the method has high transmission velocities of molecules, ions and electrons of reactants, and has high bidirectional catalytic activity of oxygen reduction / oxygen precipitation, and excellent chemical stability and mechanical strength. The method disclosed by the inention is simple in preparation process, and the obtained integral air electrode catalysis material has great application prospects in applicationin metal-air batteries such as lithium air batteries, sodium air batteries, aluminum air batteries and zinc air batteries, fuel batteries, electrochemical reactors such as hydrogen peroxide synthesisand electrochemical oxygen production, and the like, and in commercial development.
Owner:TAIYUAN UNIV OF TECH
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