A clean and efficient gas fire extinguishing agent composition comprises, with the molar volume as the benchmark, 5%-15% of 2-bromine-3,3,3-trifluoropropene (BTP) and 95%-85% of a hydrofluoroalkane fire extinguishing agent or an inert gas fire extinguishing agent. The hydrofluoroalkane fire extinguishing agent comprises one or more of heptafluoropropane, pentafluoroethane, trifluoromethane and 1,1,2,2,3,3,4-heptafluorocyclopentane. The inert gas fire extinguishing agent comprises one or more of nitrogen and carbon dioxide. By the adoption of the gas fire extinguishing agent composition, the fire extinguishing concentration of inert gas can be increased, the storage capacity is reduced, the global warming potential of hydrofluoroalkane is lowered, the environment is improved, the fire extinguishing effect is enhanced, the property is stable, no precipitation is generated after long-time storage, the raw materials are obtained easily, and the production cost is low.