35 results about "Methyl n-Butyl Ketone" patented technology

The invention discloses a method for synthesizing tetrabenazine. The method comprises: step one, using a dimethylamine aqueous solution and a formaldehyde aqueous solution as initial materials to be reacted1 to obtain tetramethyl methane diamine; step two, dissolving the tetramethyl methane diamine obtained in the step one in an organic solvent, dropwise adding acetyl chloride and 5- methyl-2-hexanone, and performing amine methylation to obtain an intermediate 3-[(dimethyl amino) methyl]-5-methyl-2-hexanone; and step three, reacting the 3-[(dimethyl amino) methyl]-5-methyl-2-hexanone obtained in the step two with 6,7-dimethoxy-3,4-dihydroisoquinoline hydrochloride to obtain the tetrabenazine. According to the method for synthesizing tetrabenazine, the cheap and accessible materials are used as the initial materials, imine salts serve as amine methylation reagents to perform amine methylation reaction on the 5- methyl-2-hexanone, and accordingly, the region-selectivity of chemical reactions is improved; and water serves as a reaction solvent to prepare the tetrabenazine, so that the operation is simple and convenient, no complex post-processing process exists, and good industrial application prospects are provided.

The green additive for welding and cutting natural gas consists of ethanol 5-10 wt%, 2-hexanol 5-10 wt%, 2-hexanone 5-10 wt%, limonene 10-15 wt%, organoplatinum 0.02-0.08 wt%, and C5-C7 isoalkane for the rest. It is liquid with high oil solubility, low boiling point and high solubility in natural gas, and may be added into liquid one gaseous natural gas in any ratio. It is non-toxic and environment friendly, and can raise the combustion temperature of natural gas greatly to 3450 deg.c. In addition, it can lower the use cost of natural gas obviously.

It is an object of the present invention to provide an inexpensive and efficient industrial method for obtaining (S)-2-pentanol, (S)-2-hexanol, 1-methylalkyl malonic acid and 3-methyl carboxylic acid at a high optical purity. The present invention provides a method of producing (S)-2-pentanol or (S)-2-hexanol which comprises allowing certain types of microorganisms or transformed cells, a product obtained by treating said microorganisms or cells, a culture solution of said microorganisms or cells, and / or a crude purified product or purified product of a carbonyl reductase fraction obtained from said microorganisms or cells, to act on 2-pentanone or 2-hexanone.

Provided are methods of forming photolithographic patterns using a negative tone development process. Also provided are coated substrates and electronic devices formed by the methods. The methods find particular applicability in the manufacture of electronic devices. The method includes: (a) providing a substrate comprising over a surface thereof one or more layer to be patterned; (b) applying a layer of a photoresist composition over the one or more layer to be patterned, the photoresist composition comprising a resin comprising an acid cleavable group and an acid generator; (c) patternwise exposing the photoresist composition layer to actinic radiation; and (d) applying a developer to the photoresist composition layer, wherein unexposed portions of the photoresist layer are removed by the developer, leaving a photoresist pattern over the one or more layer to be patterned. The developer comprises 2-heptanone and / or 5-methyl-2-hexanone.

The invention relates to a method for selectively determining residual vinyl acetate in white latex for cigarette through static headspace and gas chromatography mass spectrometry, belonging to the technical field of physical and chemical inspection of materials for the cigarette, and provides a quantitative selected ion determining method through the static headspace and gas chromatography mass spectrometry, aiming at selectively determining the residual vinyl acetate in white latex for the cigarette. A sample of the white latex for the cigarette after static headspace at 80 DEG C for 15 minutes is detected by taking 2-hexanone as an internal standard through HP-INNOWAX column in a GC-MS / SIM (Gas Chromatography Mass Spectrometry / Selected Ion Monitoring) mode, and is quantified through an internal standard method. According to the method for selectively determining the residual vinyl acetate in the white latex for the cigarette through the static headspace gas chromatography mass spectrometry, disclosed by the invention, detection limit, labeling recovery ratio and RSD (Relative Standard Deviation) of the method are respectively 0.63mg / kg, 104-107% and 2.5-4.9%; in addition, the method disclosed by the invention has the characteristics of simpleness, fastness, accuracy, sensitiveness and the like, and is especially suitable for quantitative analysis on the residual vinyl acetate in the white latex for the cigarette.

The present invention discloses a method for simultaneously measuring acetic acid vinyl ester and 6 benzene series substances in water-based adhesive. The method comprises: dispersing samples by using N-N dimethylformamide, quantifying by using double internal standard methods and simultaneously measuring 7 compounds in cigarette water-based adhesive by using a headspace-gas chromatography-mass spectrometer during one sample injection; under adopted chromatographic conditions, chromatographic peaks of benzene, toluene, ethylbenzene, orthoxylen, m-xylene / p-xylene (m-xylene and p-xylene are not separated due to problems of a chromatographic column, but the calculation results are not influenced), and acetic acid vinyl ester target substance as well as two internal standard substances, namely isobutanol and 2-hexanone, are separated well. Results show that the regression equation correlation coefficient of each component reaches 0.999 or more, the quantitative determination limit of the benzene series substances is 0.01-0.02mg / kg, the quantitative determination limit of acetic acid vinyl ester is 0.10mg / kg, the mean relative standard deviation is 1.15%-3.75%, the adding standard recovery is 88.09%-95.44%; the method is fast, accurate, good in repeatability, high in recovery rate, good in practicability, and the like.

It is an object of the present invention to provide a low-cost and efficient industrial process for producing (S)-2-pentanol, (S)-2-hexanol, 1-methylalkylmalonic acid and 3-methylcarboxylic acid with high optical purity. There is provided a process for producing (S)-2-pentanol and (S)-2-hexanol, comprising causing a certain type of microbe or transformed cells, a treatment mixture from the microbe or cells, a culture solution of the microbe or cells and / or a product of crude purification or purification of a carbonyl reductase fraction obtained from the microbe or cells to act on 2-pentanone and 2-hexanone, respectively.

The invention provides a method for preparing biogasoline by catalytic hydrogenolysis on straws. The method comprises the following steps: successively adding the straws, iodide, a metal catalyst, water, an organic solvent and inorganic acid in a reaction container according to a certain rate of charge, after feeding hydrogen until pressure in the reaction container reaches a certain range, heating the reaction container to a certain temperature and then reacting for a certain time, then cooling to a room temperature and collecting an organic phase. The prepared product mainly comprises 2-methyltetrahydrofuran, 2-methyl furan, 2,5-dimethyl tetrahydrofuran, 2,5-dimethylfuran, 2-hexanone, 3-methylcyclopentanone, 2,5-hexanedione and 5-methylfurfural. By the method, the straws are catalytically hydrogenated by metal under the conditions of low temperature and low pressure, and cellulose and hemicellulose portions in the straws are directly converted into furan, furfural and a cyclic ketones compound at high yield.

The invention discloses bacillus aryabhattai as well as a metabolite and an application thereof and aims to solve the technical problem that wilt control of plants is not satisfactory in the prior art. The bacillus aryabhattai CGMCC NO.18285 can effectively inhibit rhizopus microsporus and can be used for controlling and treating plant diseases caused by rhizopus microsporus, so that the purpose of avoiding or reducing pesticide application is achieved, sustainable development of agriculture is ensured, and the bacillus aryabhattai has broad application prospects; and the bacillus aryabhattaiCGMCC NO.18285 can metabolize and secrete a large quantity of volatile substances 5-methyl-2-hexanone, and first research finds that 5-methyl-2-hexanone has a good rhizopus microsporus inhibition function.

The invention discloses a method for measuring content of benzene and benzene series in glycerol triacetate. The method comprises the following steps: preparing a standard working solution, analyzing by gaschromatographic mass spectrometry, drawing a standard curve, calculating a result, etc. After the improvement and optimization, the detection method has the advantages of simplicity, accuracy and sensitivity in operation, high recovery rate, good repeatability and the like. 2-hexanone is used as an interior label, so that by adopting the interior label quantitative detection, errors caused by the preparation process of a sample, different sample loading amounts or instrument precision and the like can be effectively reduced; the adopted chromatographic condition enables the separation degree of six target compounds and interior label chromatographic peaks to be better; moreover, the linear correlation property is better. The detection limit is 0.01 microgram / gram to 0.02 microgram / gram, the quantitative limit is 0.04 microgram / g to 0.06 microgram / gram, the loading recovery rate is 94 percent to 104 percent, and the average relative standard deviation is within 7 percent.

The invention discloses a catalyst used for preparing N-(1,4-dimethylpentyl)-p-phenylenediamine, a preparation method thereof, and a preparation method of N-(1,4-dimethylpentyl)-p-phenylenediamine. The catalyst comprises a catalyst carrier and active components comprising copper-nickel-chromium-palladium-zinc. In the above catalyst, copper-nickel-chromium-palladium-zinc are adopted as active components. During a process for preparing N-(1,4-dimethylpentyl)-p-phenylenediamine through a condensation reduction reaction and with p-phenylenediamine or p-nitroaniline and 5-methyl-2-hexanone as raw materials, the provided catalyst is used for catalyzing the condensation reduction reaction. With the catalyst, the obtained N-(1,4-dimethylpentyl)-p-phenylenediamine has relatively high purity and conversion rate. Also, the reaction is simple and is easy to operate.

A method of detecting hypoxia. Detecting hypoxia includes detecting, in exhaled breath, at least one indicator for hypoxia. The at least one indicator is selected from the group consisting of pentanal, 2-pentanone, 2-hexanone, 2-heptanone, 2-cyclopenten-1-one, and 4-butyrolactone.

The invention relates to a dodecafluoro-2-methyl-3-pentanone-containing fire extinguishing agent composition, which comprises 50-65 wt% of dodecafluoro-2-methyl-3-pentanone, 20-30 wt% of 6-fluoro-2-hexanone, 10-30 wt% of unsaturated oil, and 1 wt% of a covering flavoring agent, wherein the unsaturated oil is selected from palmitoleic acid, linolenic acid and ricinoleic acid. The dodecafluoro-2-methyl-3-pentanone-containing fire extinguishing agent composition of the present invention has characteristics of high fire extinguishing efficiency, good environmental protection performance and no toxicity, and can be effectively used for various fire disasters.

The invention provides an application of methyl n-butyl ketone as a phenol-containing wastewater dephenolizing extractant, and a phenol-containing wastewater treatment method. The phenol-containing wastewater treatment method is characterized in that phenol-containing wastewater is extracted by using a dephenolizing extractant to obtain an extract phase and a raffinate phase, and the dephenolizing extractant contains methyl n-butyl ketone. Phenol substances in the phenol-containing wastewater can be effectively removed through adopting the method. Additionally, a high monophenol and polyphenol distribution coefficient can be obtained by adopting the dephenolizing extractant containing methyl n-butyl ketone at a high extraction temperature in order to alleviate obstruction of a heat exchanger between a deacidification and deamination tower and an extraction tower and reduce the use amount of recirculated cooling water, so the dephenolizing extractant has extremely good industrial application prospect.

The invention discloses a food-borne lactobacillus for improving the tobacco leaf quality, and a preparation method and application thereof, and belongs to the technical field of application microorganisms. The lactobacillus can be used as the unique nutrition source in the tobacco leaf obtained through the screening from pickled radish; the classification name is Lactobacillus plantarum L15; thepreservation number is CCTCC M 2017459. The L15 bacterium suspension is used for cut tobacco fermentation; the sensory smoking evaluation result shows that after the fermentation, the aroma quality ofthe cigarette is improved; the smoke is soft; the miscellaneous gas, the irritation and the bitter and spicy flavor are reduced; the sour aroma is obvious; the aftertaste is improved; after the fermentation, the major chemical ingredient proportion of the cut tobacco is more harmonious; through the aroma component analysis, the result shows that the total acid (particularly acetic acid), total alcohol and total ester contents in the fermented cut tobacco are increased; the total aldehyde ( particularly 3-methyl-Butanal), total ketone (particular 2-hexanone), total alkene, total benzene and total furan contents are decreased; the cigarette quality is improved.

A continuous preparation method of N,N'-bis(1,4-dimethylpentyl)-p-phenylenediamine includes the steps of: 1) performing a reaction to p-nitroaniline or p-phenylenediamine with 5-methyl-2-hexanone and acid in a first reactor to obtain a first material; 2) feeding the first material into a first distillation kettle, and withdrawing 5-methyl-2-hexanone from the top of the distillation kettle and withdrawing a kettle liquid to obtain a second material; 3) feeding the second material into a second reactor, in which palladium, platinum, nickel or the like solids or a supported catalyst thereof is disposed, and feeding hydrogen to perform a reaction to obtain a third reaction solution; and 4) feeding the third reaction solution into a second distillation kettle to perform distillation to obtain the N,N'-bis(1,4-dimethylpentyl)-p-phenylenediamine. The method can avoid a phenomenon that a large amount of alcohol is converted into ketones, which commonly exists in one-step reaction in a kettle reactor a fixed bed reactor, and greatly reduces recovery and treatment cost of the raw material ketone, thereby reducing material consumption and energy consumption.

The invention discloses a method for continuous removal of impurities in cyclohexanone. According to the invention, two adsorbing devices are connected in series; an adsorbent is added into the adsorbing devices for continuous adsorption of impurities in cyclohexanone; and when the total content of impurities discharged by one of the adsorbing devices is greater than 30 ppm, the adsorbing device is subjected to desorption and the other adsorbing device is used for continuous adsorption of impurities in cyclohexanone at the same time. The method provided by the invention effectively removes impurities consisting of 2-heptanone, caproic aldehyde and 2-hexanone in cyclohexanone and allows the total content of the impurities to be less than 300 ppm, which meets requirements of chemical fiber-grade cyclohexanone; and the method can carry out continuous adsorption and desorption, so continuous controllable operation is realized.

This study illustrates a simple and efficient method for the synthesis of tetrabenazine and its intermediates. First, take paraformaldehyde, dimethylamine hydrochloride, and 5-methyl-2-hexanone as raw materials to synthesize the key intermediate 3-dimethylaminomethyl-5-methyl-2-hexanone; secondly, to The crude product is effectively optimized by a simple chemical purification operation to obtain a key intermediate with higher purity; finally, using water as a solvent under the action of a catalyst, the purified key intermediate and 6,7-dimethoxy-3,4 ‑ Dihydroisoquinoline hydrochloride condensation to obtain tetrabenazine crude product, recrystallization can obtain tetrabenazine product, HPLC purity greater than 99.5%. The method uses simple chemical raw materials to obtain key intermediates with high purity through synthesis and purification, thereby further obtaining tetrabenazine products with good purity; the method has easy-to-obtain raw materials, simple operation, no need for special equipment, and high yield , get tetrabenazine with high purity.

The invention discloses a high-toughness packaging material which sequentially comprises an aluminum foil composite film layer, an adhesive layer and a cyclopentadiene film layer from inside to outside. The adhesive layer is prepared by the following steps: adding dipropanediol diacrylate and maleic anhydride into butanone, and reacting under reflux for 50 minutes; adding tetrazole and ethoxylated trimethylolpropane triacrylate, and reacting under reflux for 20 minutes; sequentially adding 1,3,5-triglycidyl-S-triazinyltrione and diethyl phosphite, and reacting under reflux for 2 hours; adding cyanochitosan, polydimethylsiloxane and 2-hexanone, and reacting under reflux for 1.5 hours; and finally, adding rubidium carbonate, continuing reacting for 1 hour to obtain the adhesive layer. By using the reasonable structural design and adhesive layer, the high-toughness packaging material disclosed by the invention has the advantages of favorable mechanical strength, high temperature resistance, favorable packaging protecting property, no pollution and the like, and is convenient to use.

The invention discloses an environment-friendly additive for natural gas welding gas. The additive is composed of the following components in percentage by weight: 5 to 10% of ethanol, 5 to 10% of 2-hexanol, 5 to 10% of 2-hexanone, 10 to 15% of limonene, 0.02 to 0.08% of organic platinum, and the balance being at least one of C5-C7 isoparaffin; wherein the organic platinum is at least one of triphenyl phosphine platinum, triphenyl phosphine platinum chloride, diamino-cyclohexane platinum oxalate, bis(benzonitrile) platinum dichloride, and ethylene diamine platinum. The using cost of natural gas welding gas is prominently reduced, moreover, the additive is harmless to the environment, and thus the additive is worthy to popularize and use in various corresponding occasions.

Provided are a resin composition, a resin formed product and a multilayer structure that are superior in long-run workability in melt molding, and are capable of forming an article exhibiting inhibited coloring and generation of defects such as streaks and fish eyes and having superior appearance characteristics while generation of an odor is inhibited. The resin composition contains an ethylene-vinyl alcohol copolymer (A) and a saturated carbonyl compound (B) having 3 to 8 carbon atoms, wherein the saturated carbonyl compound (B) is a saturated aldehyde (B-1), a saturated ketone (B-2) or a combination thereof, and the content of the saturated carbonyl compound (B) is 0.01 ppm or greater and 100 ppm or less. The saturated aldehyde (B-1) is preferably propanal, butanal, hexanal or a combination thereof. The saturated ketone (B-2) is preferably acetone, methyl ethyl ketone, 2-hexanone or a combination thereof.

The invention discloses a simple synthetic process of an antidepressant medicine imipramine hydrochloride intermediate. The simple synthetic process includes the following steps: (1) putting 6-amino-2-hexanone, BOC anhydride and DCM into a reaction bottle, and stirring the mixture at a room temperature until the raw materials completely react to form a concentrate; (2) adding AIBN and NBS into theconcentrate, heating the AIBN, NBS and concentrate to reflux, keeping the temperature until the reaction is complete, filtering, leaching a filter cake once with DCM, collecting a filtrate, washing the filtrate one with brine, drying the filtrate with anhydrous sodium sulfate, and reducing the pressure for condensation until the filtrate is dry so as to obtain a crude product; and (3) putting thecrude product into tetrahydrofuran, reducing the temperature to a room temperature, adding 60% sodium hydride soaked and washed twice with methyl tertiary ether into a reaction solution in batches, keeping the temperature until the reaction is complete, pouring the mixture into ice water for extraction twice with methyl tertiary ether, combining organic phases, washing the organic phases with brine, drying the organic phases with anhydrous sodium sulfate, increasing the pressure for condensation, and reducing the pressure for rectification to obtain the final product with the purity being 98.5% and the total yield of the three steps being 61.5%. The synthetic process has the advantages of easily available raw materials, convenient operation and high yield.

The invention relates to a method for selectively determining residual vinyl acetate in white latex for cigarette through static headspace and gas chromatography mass spectrometry, belonging to the technical field of physical and chemical inspection of materials for the cigarette, and provides a quantitative selected ion determining method through the static headspace and gas chromatography mass spectrometry, aiming at selectively determining the residual vinyl acetate in white latex for the cigarette. A sample of the white latex for the cigarette after static headspace at 80 DEG C for 15 minutes is detected by taking 2-hexanone as an internal standard through HP-INNOWAX column in a GC-MS / SIM (Gas Chromatography Mass Spectrometry / Selected Ion Monitoring) mode, and is quantified through an internal standard method. According to the method for selectively determining the residual vinyl acetate in the white latex for the cigarette through the static headspace gas chromatography mass spectrometry, disclosed by the invention, detection limit, labeling recovery ratio and RSD (Relative Standard Deviation) of the method are respectively 0.63mg / kg, 104-107% and 2.5-4.9%; in addition, the method disclosed by the invention has the characteristics of simpleness, fastness, accuracy, sensitiveness and the like, and is especially suitable for quantitative analysis on the residual vinyl acetate in the white latex for the cigarette.

Provided is a diluent for fluorinated polyurethane enamel. The diluent is formed by a component A and a component B. The component A comprises, by mass parts, 30-60 parts of methyl n-butyl ketone, 20-40 parts of dimethylbenzene and 20-40 parts of ethyl dither acetic ester; and the component B comprises, by mass parts, 50-70 parts of cyclohexanone, 10-30 parts of butyl acetate and 10-30 parts of dimethylbenzene. The diluent with the component A and the component B becomes a mixed diluent after being mixed, the fluorinated polyurethane enamel can be dispersed evenly in the mixed diluent, the surface drying time of the fluorinated polyurethane enamel is effectively controlled, and a sprayed product has the advantages that the product is flat and smooth in appearance and a paint film is uniform and continuous.

The invention relates to a magnetic composition and a preparation method of the magnetic composition. The preparation method comprises the steps of sequentially adding 1,3,5-triglycidol-S-triazinetrione and dibutyltin oxide in 2-hexanone, then adding ethoxylated trimethyol propane triacrylate and linseed oil after uniform mixing, proceeding reflux reaction for three hours, finally adding a mixture formed by a packing system and acrylic prepolymer, proceeding reflux reaction for one hour, and removing a solvent through volatilization so as to obtain the magnetic composition. According to the magnetic composition and the preparation method, disclosed by the invention, raw materials are easy to get, complex reaction in the prior art is not needed, the prepared magnetic composition has excellent mechanical property and a good solidification effect, and ingredients cooperate with one another to promote organic chain segments to move so as to form a stable structure, so that the brittleness resistance of a system is further increased, the toughness and the thermal resistance of materials are increased, and unexpected effects are obtained.

The invention discloses a catalyst used for preparing N-(1,4-dimethylpentyl)-p-phenylenediamine, a preparation method thereof, and a preparation method of N-(1,4-dimethylpentyl)-p-phenylenediamine. The catalyst comprises a catalyst carrier and active components comprising copper-nickel-chromium-palladium-zinc. In the above catalyst, copper-nickel-chromium-palladium-zinc are adopted as active components. During a process for preparing N-(1,4-dimethylpentyl)-p-phenylenediamine through a condensation reduction reaction and with p-phenylenediamine or p-nitroaniline and 5-methyl-2-hexanone as raw materials, the provided catalyst is used for catalyzing the condensation reduction reaction. With the catalyst, the obtained N-(1,4-dimethylpentyl)-p-phenylenediamine has relatively high purity and conversion rate. Also, the reaction is simple and is easy to operate.

The invention discloses a method for determining oxygenated compound of C6 in gasoline or a micro-reaction product by gas chromatography. The method comprises the following steps: introducing a determined sample to a sampling opening of a gas chromatography and enabling the determined sample to enter a nonpolar chromatographic column after the determined sample enters a pretruncating column, back-flushing heavy components with boiling point greater than that of n-undecane out of the gas chromatography by changing the pressure program of the chromatographic column after the components with boiling point being not greater than that of the n-undecane flow out from the pretruncating column, regulating the connection position of an electromagnetic valve, detecting through a flame ionization detector after the components separated from the nonpolar chromatographic column enter the strongly polar chromatographic column, changing the position of the electromagnetic valve after 2-hexanone flows out from the nonpolar chromatographic column and enters the strongly polar chromatographic column, so as to enable the carrier gas flowing by the nonpolar chromatographic column to flow to a damping column and the components with boiling point higher than that of 2-hexanone to directly enter another flame ionization detector for detection. According to the method, the lower detection limit of the oxygenated compounds can be reduced.