The invention discloses a preparation method for a
titanium dioxide nano particle
fluorescence probe for detection DDT. In the method, TiO2 is used as a core, and modified with 4-chloro-7-nitrobenzofuran
fluorescence probe and aminopropyl functional groups on the surface, and at last quasi target molecules are printed on the surface, so that a
silicon dioxide printed shell layer is formed. The preparation process of the
fluorescence probe comprises three steps of 1, preparation of a fluorescence precursor; 2,
silanization of the quasi target molecules, and 3, preparation and
elution of the
titanium dioxide nanoparticles printed with the quasi target molecules. The target molecule DDT enters a recognition site, a
helium atom of the DDT and a
hydrogen atom of aminopropyl form a
hydrogen bond, so that the aminopropyl is stable, when in optical excitation, electrons of the
nitrogen atom on the aminopropyl is prevented from being transferred to an NBD-APTS compound, fluorescence strength of the compound is enhanced according to a
photoinduced electron transfer mechanism, recognition and detection of the DDT molecule are achieved by matching print sites and changing the fluorescence strength,
photocatalysis of TiO2 is excited by changing an
excitation wavelength, and thus degradation of the DDT molecule is achieved.