900 results about "Polythiophene" patented technology

Electrolytic capacitors having low equivalent series resistance and low leakage current are described. The electrolytic capacitors include a solid electrolyte layer of a conductive material in particular a conductive polymer, and an outer layer that includes binders, polymeric anions and conductive polymers (e.g., polythiophenes). Also described is a method of preparing electrolytic capacitors that involves forming the conductive polymer of the solid electrolyte layer in situ by means of chemical oxidative polymerization or electrochemical polymerization. Electronic circuits that include the electrolytic capacitors are also described.

Compositions are provided comprising aqueous dispersions of polythienothiophenes and colloid-forming polymeric acids. Films from invention compositions are useful as hole injection layers in organic electronic devices, including electroluminescent devices, such as, for example, organic light emitting diodes (OLED) displays, as hole extraction layers in organic optoelectronic devices, such as organic photovoltaic devices, and in combination with metal nanowires or carbon nanotubes in applications such as drain, source, or gate electrodes in thin film field effect transistors.

Conductive polymers having a star structure comprising a central core with multiple attachment sites and conjugated charge transporting arms radiating therefrom. The cores are derived from hyperbranched polymers, dendrimers, or other molecules with a multiplicity of attachment sites. The arms are derived from conjugated oligomers and polymers such as polythiophene, polyaniline or polyphenylene. The subject polymers allow assembly of the macromolecules in all three dimensions in the solid state. A ramification of the compact assembly is the realization of highly reflective, smooth coatings simply applied from solution. A preferred embodiment having a 1,3,5 hyperbranched polyphenylene core and poly (3-hexylthiophene) arms provides lustrous reflective gold coatings.

Optically transparent, conductive polymer compositions and methods for making them are claimed. These conductive polymer compositions comprise an oxidized 3,4-ethylenedioxythiopene polymer, a polysulfonated styrene polymer, single wall carbon nanotubes and / or metallic nanoparticles. The conductive polymer compositions can include both single wall carbon nanotubes and metallic nanoparticles. The conductive polymer compositions have a sheet resistance of less than about 200 Ohms / square, a conductivity of greater than about 300 siemens / cm, and a visible light (380-800 nm) transmission level of greater than about 50%, preferably greater than about 85% and most preferably greater than about 90% (when corrected for substrate). The conductive polymer compositions comprising single wall carbon nanotubes are made by mixing the oxidized 3,4-ethylenedioxythiopene polymer and polysulfonated styrene polymer with single wall carbon nanotubes and then sonicating the mixture. The conductive polymer compositions comprising metallic nanoparticles are made by a process of in situ chemical reduction of metal precursor salts.

Electrolyte capacitors containing certain polythiophenes are described. More particularly, the polythiophenes have backbones containing repeating units of the following general formula (I) and / or repeating units of the following general formula (II),wherein A is, for example, a C1-C5-alkylene radical, R is, for example, a C1-C18-alkyl radical, and x is an integer from 0 to 8. Also described are dispersions comprising such polythiophenes, and the use of such polythiophenes or dispersions thereof for producing conductive layers.

Disclosed are compositions formed by a method for exchanging the water in an optionally substituted polythiophene dispersion with a specific mixture of organic solvents. The resulting compositions exhibit improved electrical conductivity, optical transparency, environmental stability, excellent adhesion to a variety of substrates and processing characteristics. Also disclosed are methods for making and using such compositions.

Compositions and methods of making the compositions comprises at least one polymer selected from polypyrrole, polythiophene, or mixtures and at least one colloid-forming polymeric acid and at least one organic liquid. New compositions are useful in electrically conductive and semiconductive layers in electronic devices among other applications. Also provided is a method of making such compositions.

Electrolytic capacitors having low equivalent series resistance and low leakage current are described. The electrolytic capacitors include a solid electrolyte layer of a conductive material in particular a conductive polymer, and an outer layer that includes binders, polymeric anions and conductive polymers (e.g., polythiophenes). Also described is a method of preparing electrolytic capacitors that involves forming the conductive polymer of the solid electrolyte layer in situ by means of chemical oxidative polymerization or electrochemical polymerization. Electronic circuits that include the electrolytic capacitors are also described.

The new fluorocarbon-functionalized and / or heterocycle-modified polythiophenes, in particular, α,ω-diperfluorohexylsexithiophene DFH-6T can be straightforwardly prepared in high yield and purity. Introduction of such modifications to a thiophene core affords enhanced thermal stability and volatility, and increased electron affinity versus the unmodified compositions of the prior art. Evaporated films behave as n-type semiconductors, and can be used to fabricate thin film transistors with FET mobilities ˜0.01 cm2 Vs—some of the highest reported to date for n-type organic semiconductors.

Compositions are provided comprising aqueous dispersions of polythiophenes and colloid-forming polymeric acids. Films from invention compositions are useful as buffer layers in organic electronic devices, including electroluminescent devices, such as, for example, organic light emitting diodes (OLED) displays in combination with metal nanowires or carbon nanotubes in applications such as drain, source, or gate electrodes in thin film field effect transistors.

An electronic device containing a polythiophene wherein R represents a side chain, m represents the number of R substituents; A is a divalent linkage; x, y and z represent, respectively, the number of Rm substituted thienylenes, unsubstituted thienylenes, and divalent linkages A, respectively, in the monomer segment subject to z being 0 or 1, and n represents the number of repeating monomer segments in the polymer or the degree of polymerization.

Organic compositions of conductive polymers are provided. The compositions have at least one polymer selected from polypyrrole, polythiophene, or combinations and at least one colloid-forming polymeric acid dispersed in a liquid medium that is at least 60% by weight at least one organic liquid. Also provided is a method of making such compositions.

Compositions are provided comprising aqueous dispersions of polythiophenes having homopolymers or co-polymers of Formula I(a) or Formula I(b) and at least one colloid-forming polymeric acid. Methods of making such compositions and using them in organic electronic devices are further provided.

A transparent electrode that includes a first layer that is interposed between a substrate (e.g., of inorganic glass) and a second layer, is described. The first layer includes a conductive polymer (e.g., a polythiophene), and the second layer includes at least one polymeric anion and at least one of a polyanaline, a substituted polyaniline and a polythiophene represented by the following general formula (I), in which A may be a C1-C5 alkylene radical, R may be a linear or branched C1-C18 alkyl radical, and x is 0 to 8, provided that when x is greater than 1, each R may be the same or different. Also described is a method of preparing the transparent electrode, and articles of manufacture (e.g., an electroluminescent array) that include the transparent electrode of the present invention.

The invention discloses a three-dimensional structure constructed by using graphene as base units and a preparation method thereof. The graphene three-dimensional structure is formed by stacking and assembling graphene, the shape of the graphene three-dimensional structure is a similar cylinder or a polygonal prism, and the volume of the graphene three-dimensional structure is 0.1-100cm<3>. The graphene three-dimensional structure can contain water, methanol, ethanol, glycol and mixture molecules thereof, and can contain Li<+>, Na<+>, K<+>, Ag<+>, Ca<2+>, Ba<2+>, Mg<2+>, Ni<2+>, Co<2+>, Cu<2+>, Mn<2+>, Cd<2+>, Zn<2+>, Pb<2+>, Pt<2+>, Pd<2+>, Rh<2+>, Al<3+>, Fe<3+>, Au<3+>, Ru<3+> and Pt<4+> metal ions. The graphene three-dimensional structure has rich network space which can be used for filling Ni, Co, Cu, Mn, Fe, Au, Ag, Pt and Ru as well as alloy nanoparticles thereof, can be used for filling polypyrrole, polyaniline, polyacrylic acid, polythiophene, polyacrylamide and polyvinyl alcohol polymers, and can be used for filling protein, amino acid, sugar and enzyme biological molecules.

Remarkably, disclosed herein is a solvent-less chemical vapor deposition (CVD) method for the oxidative polymerization and deposition of thin films of electrically-conducting polymers. In a preferred embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films. In other embodiments, the method is applicable to polymerization to give other conducting polymers, such as polyanilines, polypyrroles, polythiophenes and their derivatives. The all-vapor technique uses a moderate substrate temperature, making it compatible with a range of materials, including as fabric and paper. In addition, this method allows for the coating of high surface-area substrates with fibrous, porous and / or particulate morphologies. The coated substrates may be used in organic semiconductor devices, including organic light-emitting diodes (OLEDs), photovoltaics, electrochromics, and supercapacitors.

The present invention provides a touch panel that not only demonstrates little deterioration of performance even in harsh environments at high temperature and high humidity, but is also free of the occurrence of a whitening phenomenon occurring during sudden changes in temperature and humidity, while also having superior shock resistance. Provided are a conductive laminate in which a uniform or arbitrarily patterned conductive layer containing a polythiophene-based conductive agent and an adhesive layer containing an acidic component are in direct contact over the entire surface or a portion thereof, and a touch panel in which it is used.

Electrically conducting polymer compositions are provided. The compositions comprise homopolymers and copolymers of polythiophene, polypyrrole, polyaniline, and polycyclic heteroaromatics, and combinations of those, in admixture with an organic solvent wettable fluorinated acid polymer. The acid polymers are fluorinated or highly fluorinated and have acidic groups including carboxylic acid groups, sulfonic acid groups, sulfonimide groups, phosphoric acid groups, phosphonic acid groups, and combinations thereof. The compositions may be used in organic electronic devices (OLEDs).

The invention provides a conductive graphene printing ink. The conductive graphene printing ink is composed of 0.001-80wt% of graphene, 1-60wt% of a linking material, 0.1-30wt% of an assistant, and the balance solvent. The invention also provides a preparation method of the conductive graphene printing ink. The conductive graphene printing ink has the advantages of good toughness, good die molding performance, good adhesion and good impact resistance; chemically doped graphene and chemically modified graphene in the graphene have good conductive, mechanical and thermal performances. The molecules of the chemically doped graphene comprise one or more of polyaniline, polyacetylene, polythiophene, polyparaphenylene and polypyrrole, and the functional groups of the chemically modified graphene comprise one or more of an anilino group, a pyrryl group, an imidazolyl group, a benzenesulfonic acid group, a thienyl group, a furyl group, a phenyl group, a hydroxy group, an ester group and derivative groups thereof, so the conductive performance, the mechanical performances and the dispersion stability of graphene in the printing ink are improved.

A thermochromic polymer-based temperature indicator composition which comprises a polythiophene and a carrier medium. The composition is characterized in that the polythiophene is present in the medium in an amount of about 0.05 to about 5.0% by weight based on the total weight of the composition. The structure of the compound is designed such that when the composition is placed in a heat-exchange relationship with an article, the composition will exhibit a color change when a design temperature or a temperature beyond the design temperature is reached in the article.

Disclosed are polythiophene-based conductive polymer liquid compositions of high conductivity and transparency. The compositions comprise 16-32 weight % of an aqueous polythiophene-based conductive polymer solution, 52-80 weight % of an alcohol solvent, 1-12 weight % of an amide solvent, 0.01-0.4 weight % of a sulfonic acid group-containing monomer dopant, and optionally 2-8 weight % of an alkoxysilane. The compositions can be applied to transparent substrates to form coatings which have a surface resistance of 1 kOMEGA / square or less and a transmittance of 92% or higher. With the excellent conductivity and transparency, the compositions are useful as electromagnetic wave-shielding materials, finding numerous applications in cathode ray tube screens (TV sets and computer monitors) as well as CPP films, polyethyleneterephthalate films, polycarbonate panels, and acryl panels.

A method for the manufacturing of a Thin Film Inorganic Light Emitting Diode is disclosed. The device contains in one single layer or in a double layer a dispersion of zinc sulfide doped with a luminescent centre, and a water-compatible p-type semiconductive polymer, preferably a polythiophene / polymeric polyanion complex.

Disclosed are compositions / formulations that include: polythiophenes (A) containing recurring units represented by the following general formula (I), in which is, for example, —CH2—CH2—; and two additional polymers (B) and (C), each having SO3−M+ or COO−M+ functional groups. Also disclosed are electroluminescent arrangements having hole-injecting layers containing the disclosed compositions.

The invention relates to a super-hydrophobic washable conductive fabric and a preparation method thereof. The conductive fabric comprises a substrate fabric and a conductive polymer layer coated on the surface of the substrate fabric; the conductive polymer layer is polyaniline, polypyrrole, poly(3,4-ethylenedioxythiophene), polythiophene or their derivative polymer; and the substrate fabric is a blend fabric with the surface having cracks and the cross section having a cross shape, wherein the blend fabric is obtained by blending a heterotypic polyester synthetic fiber and a cotton fiber. The preparation method comprises the following steps: processing the substrate fabric with plasma, compositing the conductive polymer with the substrate fabric through utilizing an in situ polymerization method, and adjusting the molar ratio of a fluorine-containing doping agent and a polyaniline monomer and other reaction conditions to obtain conductive fabrics with different conductivities. The prepared conductive fabric which has the characteristics of high conductivity, rapid pH responsiveness, reversible super-hydrophobic performance, excellent washability and the like can be widely applied to development of wettability switching of acidity control, automatically cleaning fabrics, acidity detection and the like, so there are enormous business opportunities.

There is disclosed an organic electro luminescence display device comprising a two-dimensional array of pixels comprising organic electro luminescence elements capable of emitting a of color or different plural colors, each of the organic electro luminescence elements being provided with an anode, a cathode, a polymeric luminescence layer located between the anode and the cathode, and a hole injection layer. The hole injection layer is constituted by solid matters containing a donor molecule comprising polythiophene and / or a derivative thereof, and an acceptor molecule comprising polystyrenesulfonic acid and / or a derivative thereof, a concentration of sulfate ion in the hole injection layer is 125 ppm or less, and components having a molecular weight of 110,000 or less is 35% or less based on an entire solid matters, the molecular weight being converted as sodium polystyrenesulfonate in an aqueous gel permeation chromatography measured by using UV of 254 nm in wavelength.

Electrolyte capacitors containing certain polythiophenes are described. More particularly, the polythiophenes have backbones containing repeating units of the following general formula (I) and / or repeating units of the following general formula (II), wherein A is, for example, a C1-C5-alkylene radical, R is, for example, a C1-C18-alkyl radical, and x is an integer from 0 to 8. Also described are dispersions comprising such polythiophenes, and the use of such polythiophenes or dispersions thereof for producing conductive layers.

Polythiophenes which are soluble or dispersible in anhydrous or low-water-content solvents can be prepared if they are prepared in anhydrous or low-water-content solvents and a phase-transfer catalyst is added during the reaction.