The invention belongs to the field of potting materials, and discloses a high-heat-conductivity boroheteropolysiloxane potting adhesive and a preparation method thereof. The potting adhesive is composed of the following components in parts by mass: 100 parts of vinylmethyl polysiloxane, 20-100 parts of vinylmethyl nano MQ silicon resin, 5-50 parts of vinyl polyborosiloxane or vinyl borosiloxane, 0.05-0.2 part of acetylenyl cyclohexanol, 0.005-0.05 part of noble metal organic compound catalyst, 0.5-5 parts of vinyl epoxy compound, 1-10 parts of borazine, 10-0 part of methyl hydrogen-containing silicon oil and 50-120 parts of boron nitride ceramic. The high-heat-conductivity boroheteropolysiloxane potting adhesive has the advantages of high heat conductivity, favorable sealing property, high bonding force, favorable elasticity, water and moisture resistance, electric insulation, shock absorption, high temperature resistance and excellent aging resistance, and has wide application prospects in packaging of high-power electronic information components, semiconductor communication and illumination components and other components.