The invention discloses an outer rubber material for a flame-retardant red fire-fighting rubber hose and a preparation process thereof. The outer rubber material for a flame-retardant red fire-fighting rubber hose includes the following components in parts by weight: 100 parts of chlorinated polyethylene CM rubber , 8-12 parts of light magnesium oxide, 20-25 parts of magnesium hydroxide, 8-11 parts of adhesive, 0.8-1.5 parts of paraffin, 1-1.5 parts of anti-aging agent, 6-10 parts of titanium dioxide, and 5 parts of sun-fast scarlet ~6 parts, benzidine yellow 0.5~1 part, flame retardant 10~15 parts, silicon dioxide 15~25 parts, reinforcing agent 35~45 parts, light calcium carbonate 30~40 parts, dioctyl ester 30~ 35 parts, 4-5 parts of vulcanizing agent and 0.8-1.2 parts of sulfur. The outer rubber material of the invention is suitable for the production of conventional steam-vulcanized rubber hoses, and the outer rubber material of the invention has moderate deformation after vulcanization, lower elongation, no under-sulfur phenomenon, and high vulcanization safety. The product made of the outer rubber material of the invention is bright in color, excellent in aging resistance, good in flame retardant effect, safe and environmentally friendly, non-toxic, can effectively prolong the service life of the rubber hose, and reduce the production cost of the rubber hose.