The invention discloses a non-radiative multi-component composite tungsten negative material for a microwave oven magnetron and a preparation process of the negative material. The tungsten cathode material comprises lanthanum oxide, zirconium oxide, yttrium oxide, lutetium oxide, rhenium and tungsten, wherein the mass percent of each rare-earth oxide in the tungsten electrode material is 0.5%-1.5%, the mass percent of the total rare-earth oxides in the tungsten electrode is 2%-3%, the mass percent of the alloy element rhenium in the tungsten electrode material is 1%-4%, and the tungsten accounts for the rest mass percent. The tungsten cathode material is non-radiative, excellent in thermal emission performance, excellent in high-temperature creep resistance, thermal shock resistance and sag resistance, and long in service life. The preparation method of the non-radiative multi-component composite tungsten cathode material for the microwave oven magnetron comprises the steps of solution preparation, drying, reducing, isostatic cool pressing, sintering, incipient fusion, medium-frequency induction annealing, press working, winding and mechanical straightening. The non-radiative multi-component composite tungsten negative material for the microwave oven magnetron is better in usability. When heated periodically for a long time at a high temperature, the multi-component composite tungsten wire produced by virtue of the process is capable of going through large deformational resistance, and has the sag resistance.