The invention discloses a dye-sensitized solar cell (DSSC) photo-anode. The DSSC photo-anode is of a five-layer overlapped structure, and comprises a conductive matrix, a first compact layer, a transmission layer, a second compact layer and a scattering layer in sequence. The DSSC photo-anode adopts the five-layer overlapped structure, the compact layer is arranged between the conductive matrix and the transmission layer, dark current formed between electron, produced on the conductive matrix, and electrolyte is effectively restrained, and further the purpose of improving the photoelectric conversion efficiency of a DSSC is achieved. The scattering layer is arranged at the position of a porous membrane, an optical path and secondary absorption of sunlight are increased through a light scattering function of large grains, and therefore the secondary utilization efficiency of light is increased, and the photoelectric conversion efficiency of the DSSC is improved by about 20%.