The invention belongs to the technical field of Wiener electronics, and particularly relates to a gate tube material, a gate tube device and a preparation method of the gate tube device. The gate tubedevice comprises a first metal electrode layer, a second metal electrode layer and a gate layer between the two electrode layers. The chemical general formula of the gate layer material can be shownas GexTeyA100-x-y, where A in the formula is one of the elements C, B, Si, Al, Sb and Bi, x and y are atomic percentages of elements, x is greater than or equal to 10 and less than 60, y is greater than 40 and less than 90, and 100-x-y is greater than 0 and less than or equal to 25. The gate tube provided by the invention has the advantages of simplicity in preparation, capability of driving ultra-high on-state current (more than 11mA), low off-state current, high switching ratio, high switching speed and low on-voltage.