A bimetallic FMG desulfurizer for
wet oxidation desulfurization is prepared from the following raw materials in parts by weight:
ferrous salt,
manganese salt, an organic complexing agent,
metal corrole,
anthraquinone-2,7-disulfonic acid,
polyethylene glycol, an absorbent, a stabilizer, a
settling agent, a
corrosion inhibitor and a proper amount of water.
Bimetal manganese, iron ions and the like are adopted as central ions, a
metal corrole complex,
anthraquinone-2,7-disulfonic acid, an organic complexing agent and the like are adopted as ligands, inner and outer layer coordination is combined with a
supergravity technology through
weak interaction to form a supramolecular complex,
hydrogen and
oxygen in the inner and outer
layers form
hydrogen bonds, the working
sulfur capacity is high, the performance of the desulfurizing agent is stable, and oxidation regeneration is good. Moreover, the desulfurization efficiency is high, the catalytic reaction selectivity is good, secondary salt is not accumulated, and
thiosulfate is not generated. In addition, the
utilization rate of
oxygen in the regeneration process can be increased, the air consumption is reduced, the regeneration rate is increased, the
energy consumption of a
fan in the regeneration process is reduced, and the cost is low.