The invention provides a
silicon-based
molecular sieve / carbon tube
sulfur-loaded composite positive
electrode material, a preparation method and an application thereof. The technical scheme is that the preparation method comprises the following steps: mixing and
grinding a carbon tube and elemental
sulfur, adding CS2 and fully stirring, after that,
drying to obtain a carbon tube
sulfur-loaded
composite material; and mixing the carbon tube sulfur-loaded
composite material with
carbon black and
polyvinylidene fluoride according to a certain
mass ratio, then adding N-methylpyrrolidone and the
silicon-based
molecular sieve, stirring and performing
ultrasonic dispersion to be uniform, controlling the
viscosity to be 1,000 to 10,000cps to obtain
slurry, uniformly
coating the obtained
slurry on acurrent collector
aluminum foil with a thickness of 150 to 400mm, then transferring the
aluminum foil to a
drying oven at 40 to 60 DEG C to obtain the
silicon-based
molecular sieve / carbon tube sulfur-loaded composite positive
electrode material. The preparation method disclosed by the invention is simple to operate and easy for large-scale production; the prepared silicon-based molecular
sieve / carbon tube sulfur-loaded composite positive
electrode material is used for a
lithium-sulfur battery, so that the
dissolution of
polysulfide ions in liquid
electrolyte in the charging and discharging process of the
lithium-sulfur battery can be solved, a shuttle effect is effectively inhibited, and the coulombic efficiency and the
cycling stability of the
lithium-sulfur battery are improved.