The invention discloses an in-situ functional coated positive
electrode material, a preparation method thereof and an all-
solid-state
lithium battery, and belongs to the field of all-
solid-state
lithium batteries. The positive
electrode material comprises a positive
electrode active material and a functional
coating layer generated on the surface of the positive electrode active material in situ, the component of the
coating layer is Li2O, Li2CO3 or Li2OLi2CO3, and all the components have the functions of Li < + > transmission, bidirectional interface compatibility and
structural stability. A precursor of the positive electrode active material and excessive
lithium salt are uniformly mixed and sintered, part of the lithium salt participates in synthesis of the positive
electrode material, part of the lithium salt generates the thin and uniform functional
coating layer in situ on the surface of the positive
electrode material; further high-temperature
sintering can be performed to enable the coating layer to generate
oxygen vacancies and increase the Li < + > transmission property, or low-temperature
sintering can be performed to form a
composite coating layer. When the positive
electrode material is used for assembling the all-
solid-state
lithium battery, the problem of a solid-solid interface in the all-solid-state
lithium battery is solved, and the multiplying power and the cycle performance are improved. Meanwhile, the thickness of the coating layer is controllable, the preparation process is simple, expensive equipment is not needed, and
batch production can be expanded.