The invention discloses an acidolysis method of
magnesium-containing
phosphate rock. The method provided by the invention is characterized by comprising the following steps of: carrying out acidolysis on the
magnesium-containing
phosphate rock to obtain a water-soluble
calcium,
magnesium and
phosphoric acid containing acidolysis solution, carrying out acidolysis on the
phosphate rock by using the generated
phosphoric acid to generate Ca(H2PO4)2.H2O
solid, performing a reaction between H2SO4 and water-soluble
calcium to generate high-pureness
calcium sulfate whisker, and performing a reaction between water-soluble magnesium and
phosphor in the acidolysis solution and NH3 to generate character separation magnesium ions of a MgNH4PO4
solid so as to realize complete high-efficiency comprehensive utilization of the acidolyzed magnesium-containing phosphate rock. The focus of the invention is to change magnesium ions into controllable parameters which are beneficial to circulation of the acidolysis solution. The magnesium-containing phosphate rock can be efficiently utilized, and also the compound
magnesium ammonium phosphate can be used to realize the separation of
phosphor magnesium from a circulation medium HCl or HNO3 or CaCL, Ca(NO3)2, thus realizing the combination and combined production with a present
ammonium phosphate and
phosphor product processing technology. The method provided by the invention has advantages of concise technology, less investment, low
energy consumption, low cost, high benefit and no
discharge of ''three wastes (
waste gas,
wastewater and industrial residue)'', and fully presents great
business value and great resource value of the
high magnesium-containing phosphate rock.