The invention relates to an efficient comprehensive utilization method of
arsenic and
antimony in
arsenic and
antimony smoke and belongs to the technical field of non-
ferrous metallurgy. The method comprises the specific steps that the
arsenic and
antimony smoke is subjected to stge treatment,
fine powder smoke obtained through separation is put into hot water according to the formula that the liquid-
solid ratio is 5:1, agitation leaching is conducted for 60 min at the temperature is 85 DEG C, and
solid-liquid separation is conducted after leaching; an
oxidizing agent is slowly added into leaching liquid, the
volume percentage of the
oxidizing agent is 3%, stirring is continuously conducted for 60 min, and arsenic-containing leaching post-liquid and antimony-containing leaching residues are obtained after filtering; a
sodium salt solution is added into the leaching post-liquid, the mixture is subjected to low-temperature concentration and
crystallization under the
microwave condition after sufficient stirring,
sodium arsenate crystals are obtained after centrifugal filtering, and
crystallization mother liquor is used circularly; and the
sodium arsenate crystals are sent to
microwave drying equipment to be dried, and products are obtained after
drying. According to the method, the arsenic and antimony smoke is subjected to stage treatment according to the grain size, enrichment and separation of arsenic and antimony can be achieved, operation is easy, and the cost is effectively reduced; and separated arsenic-enriched smoke is leached, refined and crystallized, arsenic products are formed for export sales, antimony-containing materials return to the procedure, and resource recycling is achieved.