Disclosed is a comprehensive
recovery method for a complex material containing
arsenic and valuable
metal slags, comprising passing the materials containing
arsenic through a primary rotating
kiln to volatilize the
arsenic, and through a secondary rotating
kiln to purify the arsenic, so that an
arsenic product containing 99.5% As 2 O 3 is produced; reduction
smelting slags from the primary and secondary rotating kilns in a blowing volatilization furnace, with the
resultant highly arsenious dust being returned to the primary rotating
kiln for treatment, and the slags being used as a
raw material in a
cement manufactory and a
raw material for
zinc after undergoing strongly reductive dearsenization and volatilization of
zinc in a fuming furnace; the
resultant alloy containing arsenic being subjected to basic oxidizing refinement, and the oxidized / refined
alloy after dearsenizations containing Pb > 72%, Sb > 12%, As 2 O 3 <0.02%, being sold as a lead-
antimony alloy; the basic slags from the refinement, containing As 2 O 3 10%-20%, being subjected to crushing,
dissolution in base, and
filtration, with the slags thereof being returned to a blowing volatilization furnace for treatment; precipitating
tin from the basic solution containing
tin and arsenic by blowing in CO 2 , with the filtered
tin oxide being sold as a
raw material for tin; adding Ca(OH) 2 into the basic filtrate containing arsenic to precipitate arsenic, returning the filtered slags of
calcium arsenate to the primary rotating kiln for treatment, and evaporating the remaining basic solution to concentrate and recover the base.