The invention provides a titanium composite, which comprises lithium-titanium composite oxide and a lithium compound, wherein the lithium compound comprises the lithium-titanium compound oxide; and the lithium compound is at least one of lithium zirconate, lithium vanadate, lithium metasilicate, lithium metamanganate, lithium carbonate, lithium phosphate, lithium aluminate, lithium hydrogenphosphate, lithium hydroxide, lithium chlorate, lithium sulfate, lithium molybdate, lithium chloride, lithium borate, lithium citrate, lithium tartrate, lithium acetate and lithium oxalate. The composite can realize the high-rate and quick charge and discharge of a battery, improve the recycling performance and high temperature storage performance of materials and in particular improve the equality safety of batteries using high-performance titanium materials. The invention also provides a preparation method for the material, which is simple, easy to operate, high in yield and suitable for massive production. The composite of the invention has a wide application range, can be used alone or in combination with other electrode active materials as a cathode active material of various lithium ion batteries or an electrode material of capacitors.