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1449 results about "Hydrogen sulphide" patented technology

Treatment system and treatment method for removing hydrogen sulfide from acid gas

ActiveCN102895870ALow internal sulfur concentrationReduce the concentration of sulfurDispersed particle separationSulfur preparation/purificationPtru catalystPhysical chemistry
The invention relates to a treatment system and a treatment method for removing hydrogen sulfide from acid gas. The treatment system comprises an absorption reaction unit, a sulphur filtering unit, a solution regeneration unit, a temperature control unit and a medicament deliver unit, wherein the absorption reaction unit has a ferrum-catalyst desulfuration solution, is used for absorbing hydrogen sulfide contained in the acid gas introduced in the ferrum-catalyst desulfuration solution, and oxidizing the hydrogen sulfide into sulphur; the sulphur filtering unit is used for filtering the sulphur; and the solution regeneration unit is used for oxidizing and regenerating the filtered ferrum-catalyst desulfuration solution. The sulphur filtering unit is positioned between the absorption reaction unit and the solution regeneration unit. According to the system and the method, the sulphur is filtered from the solution before the step of oxidation and regeneration, so that the sulphur can not be deposited at the bottom end of an oxidization regenerator, the concentration of the sulphur in the system is low, so that the system can operate stably for a long time, and has good operational flexibility under various work conditions; the structure of equipment can be simplified; the investment is saved; and the construction period is also saved.
Owner:美景(北京)环保科技有限公司

Hydrotreating catalyst and processes for hydrotreating hydrocarbon oil with the same

The present invention relates to a hydrotreating catalyst composed of a carrier having a Brønsted acid content of at least 50 mumol / g such as a silica-alumina carrier or a silica-alumina-third component carrier, in which the silica is dispersed to high degree and a Brønsted acid content is at least 50 mumol / g, and at least one active component (A) selected from the elements of Group 8 of the Periodic Table and at least one active component (B) selected from the elements of Group 6 of the Periodic Table, supported on said carrier. The present invention also relates to a method for hydrotreating hydrocarbon oils using the same. The hydrotreating catalyst of the present invention provides excellent tolerance to the inhibiting effect of hydrogen sulfide, high desulfurization activity, and exhibits notable effects for deep desulfurization of hydrocarbon oils containing high contents of sulfur, in particular gas oil fractions containing difficult-to-remove sulfur compounds. The hydrotreating catalyst of the present invention is also very effective for hydrodenitrogenation, hydrocracking, hydrodearomatization, hydroisomerization, hydrofining and the like of hydrocarbon oils.
Owner:TONENGENERAL SEKIYU

Sulfur removal agent suitable for production of oil-gas well

The invention relates to a sulfur removal agent suitable for the production of an oil-gas well. The sulfur removal agent comprises the following components in percentage by mass: 10 to 25 percent of hexahydro-1,3,5-tris(hydroxyethyl)-s-triazine, 5 to 20 percent of alcohol amine, 5 to 20 percent of small molecular alcohol and the balance of water. The alcohol amine is one or a mixture of more thantwo of monoethanolamine, ethyleneglycol amine, diisopropanolamine, methyldiethanolamine and triethanolamine; and the small molecular alcohol is one or a mixture of more than two of methanol, ethanol and propanol. The sulfur removal agent has a simple formula, can be soluble with water, and can effectively reduce the content of hydrogen sulfide in crude oil or natural gas; simultaneously, productsgenerated by the sulfur removal agent and the hydrogen sulfide are water-soluble, and cannot block a mineshaft and influence the normal production of the oil-gas well; and the sulfur removal agent can achieve effects at the temperature of 30 to 120 DEG C and can be quickly reacted with the hydrogen sulfide.
Owner:SOUTHWEST PETROLEUM UNIV

Anti-Corrosion Conformal Coating for Metal Conductors Electrically Connecting an Electronic Component

An apparatus includes an electronic component mounted on a substrate and metal conductors electrically connecting the electronic component. A conformal coating overlies the metal conductors and comprises a polymer into which a phosphine compound is impregnated and / or covalently bonded. Accordingly, the conformal coating is able to protect the metal conductors from corrosion caused by sulfur components (e.g., elemental sulfur, hydrogen sulfide, and / or sulfur oxides) in the air. That is, the phosphine compound in the polymer reacts with any corrosion inducing sulfur component in the air and prevents the sulfur component from reacting with the underlying metal conductors. Preferably, the phosphine compound in the polymer does not react with other components in the air (e.g., carbon dioxide) which would otherwise deplete its availability for the target reaction. The phosphine compound may be rendered completely non-volatile by covalently bonding it directly into the polymer backbone.
Owner:IBM CORP

Liquid sulphur degassing device and liquid sulphur degassing method

The invention relates to a liquid sulphur degassing device and a liquid sulphur degassing method. The liquid sulphur degassing device comprises a liquid sulphur tank communicated with a liquid sulphur pipeline, wherein the liquid sulphur tank is internally provided with gas stripping equipment which can strip hydrogen sulphide gas in liquid sulphur, and the upper part of the liquid sulphur tank is provided with gas pumping equipment which can pump the hydrogen sulphide gas with other gases in the liquid sulphur tank out of the liquid sulphur tank; and the liquid sulphur degassing device is characterized in that the liquid sulphur tank comprises a gas stripping tank and a finished product tank, wherein an overflow dam is arranged between the gas stripping tank and the finished product tank; the liquid sulphur pipeline is communicated with the gas stripping tank; the suction inlet of the liquid sulphur pump is connected with the bottom of the finished product tank; the outlet of the gas pumping equipment is connected with the material inlet of an absorption tower; and the top of the absorption tower is provided with a waste gas outlet, the upper part of the absorption tower is provided with an absorption liquid inlet, a liquid outlet arranged at the bottom of the absorption tower is connected with a main pipeline, and the main pipeline is provided with a pressure pump which pumps out, pressurizes and conveys the liquid in the absorption tower. The liquid sulphur degassing device provided by the invention is simple in process, low in equipment investment and good in degassing effect.
Owner:ZHENHAI PETROCHEMICAL ENG CO LTD

Optoelectronic hybrid integration sensor device of sulfureted hydrogen gas concentration and test method thereof

The invention discloses an optoelectronic hybrid integration sensor device of sulfureted hydrogen gas concentration, which has the characteristics: laser light led out from a laser (1) penetrates through a lens (3) via a polarizer (2), an optical fiber (4) transmits focused polarized light into a gas box (13), the coupling of the optical fiber with a wave guide is realized on an input coupling element (12), the coupled light enters a Mach-Zehnder wave guide interferometer (14), branch wave guides (5 and 19) are respectively connected with a reference arm wave guide (15) and a signal arm wave guide (6) in parallel, the end surface sizes of the two wave guides are determined by mode field matching so as to reduce coupling loss and improve coupling efficiency, a wave guide phase modulator (16) adopts a lumped type wave guide phase modulator structure and is arranged between the reference arm wave guide and the signal arm wave guide, the light interfered by the Mach-Zehnder wave guide interferometer is coupled out of the gas box by an output coupling element (18) to enter a photoelectric signal transforming and processing system and then is led into a photoelectric diode (9) by a lens (7) and an analyzer (8) via the optical fiber, after that, the light intensity is transformed into electric signals to be inputted to a micro signal processor (10), and finally the concentration value of the sulfureted hydrogen gas is obtained by calculation.
Owner:克拉玛依市金牛工程建设有限责任公司

Heavy metal waste acid and wastewater resource recycling method and device

The invention discloses a heavy metal waste acid and wastewater resource recycling method and device. According to the method, acids in waste acid can be well separated through selection of anionic and cationic membranes in the electrodialysis process, heavy metal ions still remain in a waste acid solution, and the separated acid enters a concentration basin, has the acidity of over 8 percent and can be used for a sulfuric acid preparation process; the acidity of the treated waste acid is reduced to a pH value of over 3, valuable heavy metals in heavy metal-containing low-acidity waste liquor can be rapidly recovered by utilizing a hydrogen sulfide and jet process integration technology, and the recovery rate of the heavy metal ions is over 95 percent; the residual low-acidity low-salt wastewater can be recycled for a spraying system. According to the method, the heavy metal waste acid and wastewater can be treated at high efficiency, the phenomena that neutralization residues which are difficultly treated are generated and secondary pollution is caused in the process of neutralizing by adopting alkalis are avoided, high-quality sulfuric acid and heavy metals can be recovered, and more important, the adopted equipment and device are simple, convenient to operate and good in treatment effect.
Owner:CENT SOUTH UNIV +1

X70 pipeline steel hot rolled coil and manufacture method thereof

The invention relates to an X70 pipeline steel hot rolled coil and a manufacture method thereof. The coil comprises the following ingredients in percentage by weight: 0.02 to 0.05 percent of C, 0.10 to 0.30 percent of Si, 1.00 to 1.40 percent of Mn, at most 0.015 percent of P, at most 0.002 percent of S, 0.015 to 0.05 percent of Alt, 0.05 to 0.08 percent of Nb, 0.02 to 0.035 percent of V, 0.01 to 0.02 percent of Ti, 0.10 to 0.50 percent of Cr, at most 0.006 percent of Ca, 0.10 to 0.30 percent of Ni and 0.10 to 0.30 percent of Cu. The manufacture method is mainly characterized in that a, the laser fused (LF) refining is carried out outside a furnace: desulfurization is carried out until the weight percent of S is less than or equal to 0.0015 percent; b, the RH refining is carried out outside the furnace: Ca-Si lines are added before the vacuum smelting and steel outlet; c, the continuous casting temperature is 1553+ / -15DEG C; d, the continuous casting pulling speed is higher than or equal to 1.0 m / min; e, the plate blank heating temperature is lower than or equal to 1200 DEG C; f, the rough rolling terminating temperature is 930 to 1030 DEG C; g, the finish rolling terminating temperature is 780 to 850 DEG C; h, the steel band coiling temperature is 450 to 580 DEG C; and l, the cooling speed of the layer flow cooling is higher than or equal to 5 DEG C / s. The X70 pipeline steel hot rolled coil simultaneously meets the requirements of high toughness and hydrogen sulphide corrosion resistance of X70 pipeline steel.
Owner:SHANXI TAIGANG STAINLESS STEEL CO LTD

Regeneration method for process which removes hydrogen sulfide from gas streams

A process is provided for the removal of hydrogen sulfide out of a gaseous stream (22), such as a natural gas, by contacting the hydrogen sulfide containing gas with a sorbing liquid (26) containing a tertiary amine so that the hydrogen sulfide is sorbed into the liquid in absorber (11) and transferring the sorbing liquid/hydrogen sulfide mixture to a reactor (15) where the tertiary amine promotes the conversion of the hydrogen sulfide into polysulfide via reaction with sulfur; transferring the polysulfide solution from the reactor (15) to a regenerator (10) where polysulfide is converted into elemental sulfur via reaction with air (9); transferring at least a portion of the solution (25) containing elemental sulfur, as well as sulfate and thiosulfate species, into a mixture (36) where it is contacted with gaseous ammonia which reacts with the sulfate and thiosulfate species to produce ammonium sulfate and ammonium thiosulfate which are removed from the solution while the remaining portion of solution (25) is transferred to a sulfur recovery unit (14). That portion of the solution which has been subjected to ammonium sulfate and ammonium thiosulfate removal is rejoined with that portion of the solution (25) being forwarded to sulfur recovery unit (14). The solution from the sulfur recovery unit (14) is recycled back to the absorber (11).
Owner:URS

Device and method for comprehensively treating acidic sulfate organic waste water based on biological desulfurization

The invention belongs to the field of environmental engineering, and in particular relates to a device and a method for comprehensively treating acidic sulfate organic waste water based on biological desulfurization. The method comprises the following steps of: 1, reducing sulfate in the organic waste water, blowing hydrogen sulfide off, namely (1-1) mixing the acidic sulfate organic waste water and sulfide-containing recirculation water in an anaerobic digestion reactor, controlling the pH of the mixture to be 5.0 to 6.0, and thus obtaining a hydrogen sulfide-containing acidic mixed solution, and (1-2) introducing inert gas, blowing the hydrogen sulfide off, adding sulfate reducing bacteria, reducing the sulfate to form sulfide, obtaining the sulfide-containing recirculation water and returning to the step (1-1); and 2, absorbing, oxidizing and recycling the hydrogen sulfide, namely (2-1) absorbing the hydrogen sulfide blown off in the step (1-2) by using a weak alkaline solution, adding sulfur-oxidizing bacteria, oxidizing the hydrogen sulfide to form elemental sulfur, separating to obtain the elemental sulfur and effluent, and (2-2) treating the effluent for recycling. By the device and the method, sulfate innocent treatment and resource recovery treatment are realized.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Preparation method for hydrogenated C9 petroleum resin

InactiveCN102746458AOptimize reaction pressureGood huePtru catalystDistillation
The invention relates to a preparation method for a hydrogenated C9 petroleum resin. A technical point of the method is that: the method comprises a desulfurization process and a hydrogenation process. Steps of the desulfurization process comprise: pouring cyclohexane, toluene, and mixed aromatic hydrocarbon into a mixer, and completely mixing; heating the mixed resin solution, and adding the heated resin solution and hydrogen gas to a desulfurization hydrogenation reactor; carrying out a desulfurization reaction under an effect of a desulfurization catalyst; and carrying out high fraction separation, low fraction separation, gas stripping with a gas stripping tower, and hydrogen sulfide removing to obtain a desulfurization resin liquid. Steps of the hydrogenation process comprise: heating the desulfurization resin liquid, and adding the heated desulfurization resin liquid and hydrogen gas to a hydrogenation reactor; carrying out a hydrogenation reaction under an effect of a hydrogenation catalyst; carrying out high fraction separation and low fraction separation to obtain a hydrogenation resin liquid; and carrying out distillation on the hydrogenation resin liquid to obtain the hydrogenated C9 petroleum resin finished product. The desulfurization catalyst adopts cobalt and molybdenum as active ingredients, and the hydrogenation catalyst adopts nickel, tungsten and copper as active ingredients. The method of the present invention has characteristics of simple process, good decolorization effect, stable quality, wide application range, and the like.
Owner:盘锦和运新材料有限公司

Process for producing a purified synthesis gas stream

A process for producing a purified synthesis gas stream from a carbonaceous feedstock, the process comprising the steps of
  • (a) partial oxidation of the carbonaceous feedstock with a molecular oxygen comprising gas to obtain a synthesis gas comprising water, hydrogen sulphide, and carbon dioxide besides the main constituents carbon monoxide and hydrogen,
  • (b) mixing the synthesis gas and methanol and reducing the temperature of said mixture and separating a liquid methanol-water mixture from a cooled gaseous synthesis gas,
  • (c) contacting the cooled synthesis gas obtained in step (b) with methanol to decrease the content of hydrogen sulphide and carbon dioxide in the synthesis gas, thereby obtaining a rich methanol stream comprising hydrogen sulphide and carbon dioxide and a synthesis gas stream depleted in hydrogen sulphide and carbon dioxide;
  • (d) regenerating the rich methanol stream of step (c) by separating from the rich methanol a carbon dioxide fraction and a hydrogen sulphide fraction to obtain lean methanol, which lean methanol is used as methanol in step (b) and/or (c), and wherein
  • (e) part of the methanol in the methanol-water mixture obtained in step b) is isolated and reused in step (b) and/or (c) and wherein,
  • (f) another part of the methanol in the methanol-water mixture obtained in step (b) is recycled to step (a) under conditions such that methanol is converted into carbon monoxide and hydrogen.
Owner:SHELL OIL CO

Specific fluorescent probe for identifying hydrogen sulfide and application of probe

The invention relates to a specific fluorescent probe for identifying hydrogen sulfide and an application of the probe, belonging to the field of fine chemical engineering. The fluorescent probe is a resorufin derivative. Resorufin sodium salt, potassium carbonate and 2, 4-binitro bromobenzene are mixed in proportion in acetonitrile liquor to be heated, and finally are purified by silica gel chromatography to obtain the fluorescent probe. The fluorescent probe and a corresponding hydrogen sulfide content detection process are not interfered by matrixes and impurities in a biosystem and can be used for quantitative determination of hydrogen sulfide content in various biosystems. The fluorescent probe has high specificity and can be hydrolyzed with hydrogen sulfide after being specifically cyclized to obtain a hydrolysate with broken ether bonds. The probe is low in cost and feasible, can be obtained by chemical synthesis and is simple and feasible in synthetic process. The probe is high in sensitivity, and has good fluorescence emission spectrum characteristics (600-650nm). In the wavelength range, the background fluorescence of a biological sample is weak, so that the probe is suitable for detecting hydrogen sulfide content in cells. Hydrogen sulfide is quantitively detected by drawing a standard curve.
Owner:CHANGSHU RES INST OF DALIAN UNIV OF TECH CO LTD

Ferrous sulfide dirt neutral complexing cleaning agent and preparation method thereof

The invention relates to an equipment cleaning agent which is used in the field of petroleum and chemical industry, in particular to a ferrous sulfide dirt neutral complexing cleaning agent which is used for washing a synthesized ammonia low-temperature methanol washing unit system in the petroleum chemical industry and the coal chemical industry. The ferrous sulfide dirt neutral complexing cleaning agent is prepared from the following raw materials in parts by weight: 5 to 8 parts of sodium gluconate, 7 to 11 parts of sodium salicylate, 20 to 26 parts of gadoliniam diethylene triamine pentaacetic acid, 20 to 26 parts of sodium ethylene diamine tetracetate, 40 to 46 parts of propenoic acid-itaconic acid copolymer, 25 to 32 parts of disodium polyepoxysuccinicate, 12 to 15 parts of sodium hydroxyphenylace, 3 to 7 parts of triethanolamine, 3 to 7 parts of hydrogen peroxide, 0.1 to 0.3 part of lauryl sodium sulfate, 0.1 to 0.3 part of polydimethyl siloxane fluid and 40 to 45 parts of water. The ferrous sulfide dirt neutral complexing cleaning agent is free from generating hydrogen sulfide when cleaning the ferrous sulfide dirt and corroding the equipment and has strong capacity for complexing the iron ions, the removal speed is fast, the decontamination rate is more than 98 percent, the neutralization and passivation are unnecessary to carry out after the chemical washing, and the equipment can be put into operation immediately.
Owner:GANSU HEIMA PETROCHEM ENG
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