The invention discloses a
lithium supplement composite diaphragm, a preparation method and application, and belongs to the technical field of a
lithium secondary battery. According to the
lithium supplement composite diaphragm, a
ceramic layer and a
ceramic-lithium supplement layer are arranged at two sides of a base diaphragm; on the one hand, the
temperature resistance of the diaphragm is improved, the heat shrinkable property of the diaphragm is improved, and the occurrence of
short circuit accidents is reduced; and on the other hand, the
Lithium ions consumed in the charge /
discharge process can be timely supplemented, the
ion transport speed is improved, and the structure stability in the circulation process of the
lithium battery is improved. According to the lithium supplement composite diaphragm, the preparation method and the application, the lithium supplement layer is arranged on the surface of the
ceramic layer, potential safety hazards resulting from micropore blocking due to the fact that
metal lithium
powder directly contacts the base diaphragm can be avoided, moreover, the ceramic layer plays a role in buffering and heat dissipation, and the security of the lithium
powder in the use process is improved. Netty current collectors are employed in the
lithium battery, and the lithium ions can pass through an
anode sheet and a
cathode pole rapidly, and a high speed channel is provided to supplement the lithium ions timely.