The invention discloses a
silicon-carbon-
nitrogen composite negative
electrode material and a preparation method thereof, belonging to the field of negative
electrode materials for
lithium ion batteries. The method comprises: heating the mixture of the
silicon source and the
nitrogen source to 600-1000°C at a heating rate of 0.5-10°C / min under an
argon atmosphere, and
sintering at a temperature of 600-1000°C for 3-15 hours, Cool down to
room temperature to obtain a
nitrogen-doped
silicon-based material; mix the nitrogen-doped silicon-based material and
graphite evenly, and in a
nitrogen atmosphere, mix the nitrogen-doped silicon-based material and
graphite at a heating rate of 0.5-10°C / min The mixture is heated to 500-900° C., sintered at 500-900° C. for 1-10 hours, and cooled to
room temperature to obtain a silicon-carbon-nitrogen composite negative
electrode material. The present invention can reduce the energy
band width of the silicon material and improve its
conductivity by
doping the silicon material with nitrogen; the
volume effect of the silicon material can be effectively buffered by
coating graphite on the surface of the silicon-based material doped with nitrogen, so that The prepared silicon-carbon-nitrogen composite
anode material has excellent rate performance and cycle stability.