The invention belongs to the fields of civil engineering and environmental material engineering, and in particular relates to geo-polymer recycled concrete and a preparation method thereof. The geo-polymer recycled concrete is prepared from raw materials of recycled coarse aggregate, recycled fine aggregate, fly ash, slag powder, water, sodium silicate, sodium hydrate, naphthalene sulfonate formaldehyde condensation compound and calcium saccharate according to certain mixing proportion by adopting a special stirring process. The product of the geo-polymer recycled concrete not only has simple preparation process, but also has good working performance, mechanical property, durability and heat-insulating property. Simultaneously, the geo-polymer recycled concrete and the preparation method can efficiently use a great deal of waste concrete and two industrial byproducts of the fly ash and blast furnace slag, are significant in saving resources, saving energy sources and protecting the environment, and accord with the sustainable development strategy of the building industry. The product of the geo-polymer recycled concrete can be widely applicable to road engineering, structural engineering and other various civil engineering constructions.