The invention relates to strippable heat-proof antirust protective film coating and a preparation method thereof. The raw material of the protective film coating is formed by paint and curing agent. The paint comprises, by weight, 88-96 parts of linear chain polyester resin or acrylic resin containing hydroxide radical, 2.0-5.0 parts of stripping accelerant, 1.0-3.0 parts of film-forming accelerant, 0.5-2.0 parts of antifoaming agent and 0.5-2.0 parts of flatting agent. The curing agent comprises, by weight, 25-40 parts isocyanate polymer. The linear chain polyester resin or the acrylic resin containing the hydroxide radical is heated and stirred and then added in other components except the curing agent, the isocyanate polymer is added in the mixture during usage, and the strippable heat-proof antirust protective film coating is obtained after even mixing. The strippable heat-proof antirust protective film coating does not contain solvent, meets environment-friendly requirements, simultaneously has high waterproof performance, oil resistance, temperature resistance, abrasion resistance and strippable performance, can have metal surfaces, stripping surfaces, plastic surfaces and the like at the same time, and has temporary antirust protection effects.