The invention discloses a
phosphorus-based grouting filling material suitable for old goaf treatment. The
phosphorus-based grouting filling material is prepared through the following steps: uniformly mixing, by weight, 40-60 parts of
phosphorus slag powder, 30-40 parts of
fly ash, 6-10 parts of an active activator and 3-8 parts of an expanding agent, adding the above obtained mixture, 0.5-1.5 parts by weight of a
water reducer, 0.5-1 part by weight of a water retaining agent and 30-50 parts by weight of water to a stirring
pool, uniformly stirring, adding 100-200 parts by weight of phosphorus
tailings, and uniformly stirring. The phosphorus-based grouting filling material has the advantages of fast strength development, high filling efficiency, no shrinkage, and suitableness for long-distance pumping, the initial
setting time is not smaller than 70min, the final
setting time is not greater than 200min, the initial fluidity is not smaller than 300mm, the 30min fluidity retention value is not smaller than 260mm, the 1d
compressive strength is not smaller than 4.9MPa, the 7d comprehensive strength is not smaller than 8.8MPa, the 28d
compressive strength is not smaller than 12.9MPa, and the vertical
expansion rate is not smaller than 0.1%.