The invention discloses high-voltage electrostatic protection shell fabric formed by interweaving of warps and wefts. Both of the warps and wefts are blend fibers comprising 30-80% of metallic fibers and 20-70% of aramid fibers; further, both of the warps and wefts are blend fibers comprising 30-79% of metallic fibers, 20-69% of aramid fibers and not more than 15% of polyamide fibers, wherein the aramid fibers include at least one kind of 1313 fibers and 1414 fibers; when the aramid fibers include both of the 1313 fibers and the 1414 fibers, the 1313 fibers and the 1414 fibers can be in an optional proportion. The manufacturing technology of the high-voltage electrostatic protection shell fabric includes the steps of preparing blended yarn from fibrous raw materials, warping, sleying, weaving on a rapier loom according to the technology of 'short back beam, small tension and small opening', burling, finishing and carrying out finished product inspection. The high-voltage electrostatic protection shell fabric has the advantages of high strength, high wear resistance, high shielding performance, low resistance, fire resistance and dimensional stability.