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44results about How to "High lithium ion conductivity" patented technology

Organic/inorganic composite electrolyte and preparation method thereof

The invention discloses an organic/inorganic composite electrolyte and a preparation method thereof. The organic/inorganic composite electrolyte is obtained by dispersing a lithium salt and a modified inorganic solid electrolyte into a polymer in a mixing manner, wherein the polymer contains an ethylene oxide repeating unit. The modification of the inorganic solid electrolyte is carried out for the first time; a polymer electrolyte and the inorganic electrolyte are effectively and evenly composited, so that the organic/inorganic composite electrolyte material is obtained. The dispersion of the inorganic solid electrolyte in the polymer is improved by the modification of the inorganic solid electrolyte, so that the adverse effect that the inorganic solid electrolyte is automatically gathered is avoided. The organic/inorganic composite electrolyte material obtained according to the preparation method has the advantages of the polymer electrolyte and the inorganic electrolyte, so that the comprehensive performance of the organic/inorganic composite electrolyte material is obviously improved. The organic/inorganic composite electrolyte material has practical value and can be popularized in lithium ion secondary batteries.
Owner:TORAY ADVANCED MATERIALS RES LAB CHINA

Lithium ion battery diaphragm, preparation method of the lithium ion battery diaphragm, and lithium ion battery containing the lithium ion battery diaphragm

The invention provides a lithium ion battery diaphragm. The lithium ion battery diaphragm comprises a diaphragm base material and a solid electrolyte layer arranged on at least one surface of the diaphragm base material. The invention also provides a preparation method of the lithium ion battery diaphragm, a device adopted by the preparation method and a lithium ion battery containing the lithium ion battery diaphragm. A high rate of lithium ion transmission between positive and negative poles of the lithium ion battery containing the lithium ion battery diaphragm is kept, a risk of short circuit between the positive and negative poles is reduced, and a diaphragm heat shrinkage problem and battery safety are improved.
Owner:BYD CO LTD

Solid electrolyte, all-solid-state battery including the same, and method for making solid electrolyte

A solid electrolyte comprises a ramsdellite-type crystal structure and has low activation energy of lithium ions and good lithium ion conductivity. The solid electrolyte is represented by the general formula Li4x−2a−3b−c−2dSn4−x−c−dM(II)aM(III)bM(V)cM(VI)dO8 [wherein M(II) is a divalent cation, M(III) is a trivalent cation, M(V) is a pentavalent cation, and M(VI) is a hexavalent cation, 0≦x≦1.33], wherein in the general formula, 0<a+b+c+d, 0≦a+b≦x, 0≦c+d<0.9, and 3x−a−2b−c−2d≦2. The all-solid-state battery includes the solid electrolyte in at least one layer of the positive electrode layer, negative electrode layer, and solid electrolyte layer. The method of making the solid electrolyte includes a step of preparing a mixed powder as a raw material and heating with microwave irradiation.
Owner:HITACHI LTD

Lithium phosphate coated lithium iron phosphate electrode and preparation method thereof

The invention relates to a lithium phosphate coated lithium iron phosphate electrode and a preparation method thereof, belonging to the technical field of electrode materials for lithium secondary batteries. The surface of the lithium iron phosphate electrode is coated with nanoscale glassy state lithium phosphate. The electrode preparation method comprises the following steps of: mixing lithium phosphate powder and an organic solvent, carrying out ball-milling on the mixture to form pulp, drying the pulp to obtain powder, compacting the powder into a lithium phosphate target precursor, and then calcining to obtain a lithium phosphate target; carrying out magnetron sputtering on lithium iron phosphate electrode (serving as substrate) and the lithium phosphate target to obtain the lithium phosphate coated lithium iron phosphate electrode, wherein the distance between the target and the substrate is 4-8cm, and the background intensity of pressure is less than or equal to 10*10<-5>Pa. The electrode has high lithium-ion conductivity, and also the capacity of the electrode is improved; the coated lithium phosphate has good chemistry and electrochemical stability and can be used for protecting the stability of the electrode structure; the preparation method is simple and low in cost; and the large-scale production is easy to realize.
Owner:BEIJING INSTITUTE OF TECHNOLOGYGY

Quasi-solid-state lithium battery and preparation method thereof

The invention discloses a quasi-solid-state lithium battery and a preparation method thereof. The quasi-solid-state lithium battery comprises a negative electrode, a positive electrode and a diaphragm, and also comprises a quasi-solid-state electrolyte dispersed among the surfaces of the negative electrode, the positive electrode and the diaphragm and gaps among the negative electrode, the positive electrode and the diaphragm. The quasi-solid-state electrolyte comprises a polymer phase, and a ceramic electrolyte, a lithium salt and a flame-retardant organic solvent which are dispersed in the polymer phase, wherein the polymer phase is formed by in-situ polymerization of composite acrylate monomers; and the composite acrylate monomer comprises a star-shaped acrylate monomer and a chain-shaped acrylate monomer. According to the quasi-solid-state lithium battery disclosed by the invention, the problem that the safety of the battery is reduced by liquid electrolyte is solved, and the problem that the cycle performance of the battery is reduced due to dissolution of solid polymer electrolyte is also avoided. Therefore, the quasi-solid-state lithium battery has excellent safety performance, high conductivity and excellent cycling stability.
Owner:ZHEJIANG UNIV

Composite cathode material for lithium ion batteries and preparation method thereof

The invention relates to the field of lithium ion batteries, and specifically relates to a novel composite cathode material for lithium ion batteries. An Li3V2(PO4)3 material is taken as a core, a fast ion conductor type solid electrolyte is embedded in a carbon-coated layer, and a double coated core-shell structure is formed with carbon, the lithium ion conduction speed of the lithium vanadium phosphate material is improved in a targeted manner, the defect that the electronic conductivity of the lithium vanadium phosphate material is recovered, and the lithium ion conduction speed can also beimproved obviously, so that the performances of the lithium vanadium phosphate cathode material are improved relatively comprehensively, the impedance is reduced, the specific capacity is improved, the circulation and rate performance is improved.
Owner:UNIV OF ELECTRONIC SCI & TECH OF CHINA

Preparation method of electrolyte of all-solid-state lithium battery

The invention discloses a preparation method of an electrolyte of an all-solid-state lithium battery. According to the invention, ball-milling mixing is combined with a low-temperature solid-phase reaction to realize the method; meanwhile, the amorphous lithium-rich anti-perovskite solid electrolyte material is prepared by means of mechanical ball milling, melting and cold quenching and the like;the prepared amorphous powder material is uniformly deposited on a selected substrate through spin coating, dipping-pulling or thermal spraying to obtain a thickness-controllable thin film, so that lithium ion conductivity test, activation energy measurement and total battery assembly can be carried out; lattice constants and anti-perovskite structure factors are regulated and controlled by dopingother halogen atoms, so that the material is more suitable for lithium ion migration; and non-stoichiometric phases are generated by volatilizing halides to construct lithium ion migration channels and shelf structures. A large number of 3D fast ion transmission channels are constructed in anti-perovskite crystal lattices through multiple means, the purpose of improving the lithium ion conductivity of the electrolyte material is achieved, and therefore the durability of the all-solid-state lithium battery is improved.
Owner:YANGDE ELECTRIC GRP CO LTD

All-solid-state lithium battery positive plate, preparation method thereof and all-solid-state lithium battery

The invention provides an all-solid-state lithium battery positive plate, a preparation method thereof and an all-solid-state lithium battery. The all-solid-state lithium battery positive plate comprises a positive current collector and a functional layer coated on the positive current collector, and the raw materials of the functional layer comprise a lithium-containing active material, a conductive agent, a solid electrolyte and a polyion liquid. The all-solid-state lithium battery positive plate provided by the invention has the characteristics of relatively high ionic conductivity and thelike, and the all-solid-state lithium battery formed by adopting the positive plate has the excellent performances of relatively high ionic conductivity, relatively low impedance, relatively high discharge capacity and the like.
Owner:ZHUHAI COSMX BATTERY CO LTD

Ternary positive electrode material of lithium ion battery and preparation method of ternary positive electrode material

ActiveCN113363476AImproves the effects of reduced ionic conductivityHigh lithium ion conductivitySecondary cellsPositive electrodesElectrical batteryPhysical chemistry
The invention discloses a ternary positive electrode material of a lithium ion battery and a preparation method of the ternary positive electrode material. The ternary positive electrode material comprises a ternary material and a coating layer coated on the surface of the ternary material, wherein the coating layer comprises a Li < 2 + x > C < 1-x > Bx O3 coating agent, and x is greater than 0 and less than 1. The preparation method comprises the steps of (1) mixing a ternary positive electrode material precursor with a lithium source and a doping agent, and carrying out primary calcination to obtain primary calcined sample powder; (2) dispersing the primary calcined sample powder into an alkaline solution, stirring to fully wet the primary calcined sample powder, performing suction filtration, drying in a vacuum environment, and performing secondary calcination to obtain secondary calcined sample powder; and (3) uniformly mixing the secondary calcined sample powder with a coating material comprising a Li < 2 + x > C < 1-x > Bx O3 coating agent, and performing tertiary calcination. By improving the coating agent and the preparation method, the surface of the ternary positive electrode material is coated with a layer of material with relatively high lithium ion conductivity, so that the capacity performance and the cycle performance of the battery are effectively improved.
Owner:WANXIANG 123 CO LTD

Composite lithium titanate thin film as well as preparation method and application thereof

The invention provides a composite lithium titanate thin film as well as a preparation method and an application thereof. The preparation method of the composite lithium titanate thin film comprises the following steps of carrying out co-sputtering treatment on a lithium titanate target material and an energy density contribution main body element target material in an inert atmosphere, and growing the composite lithium titanate thin film on a substrate. According to the preparation method of the composite lithium titanate thin film, the lithium titanate target material and the energy densitycontribution main body element target material are directly deposited and formed by adopting a co-sputtering method. Therefore, the grown composite lithium titanate thin film has a rich channel structure and is stable in structure, so that high lithium ion transmission rate can be provided, and high cycling reversibility and relatively high specific capacity are maintained; and meanwhile, the direct contact of an electrolyte and a nano-scale energy density contribution main body element is effectively prevented, the irreversible side reaction between the electrolyte and the energy density contribution main body can be reduced and blocked, and the generation of a solid electrolyte membrane (SEI) is reduced.
Owner:GUILIN UNIV OF ELECTRONIC TECH

Method of preparing sulfide-based solid electrolyte for all-solid battery having argyrodite-type crystal structure

Disclosed is a method of preparing a sulfide-based solid electrolyte for an all-solid battery having an argyrodite-type crystal structure through a solution process. The method including obtaining a precursor solution by dissolving lithium sulfide, phosphorus sulfide and a halogen compound in a solvent, obtaining a precursor powder by removing the solvent from the precursor solution. Solid electrolyte for an all-solid battery can be produced by such method.
Owner:HYUNDAI MOTOR CO LTD +1

Separator for an energy store and an energy store

A separator for an energy store. The separator may be used in a lithium-sulfur battery in particular. To achieve improved cycle stability, the separator has at least one first layer and at least one second layer, the at least one first layer containing a material having an affine property with respect to at least one active electrode material, and the at least one second layer containing a material having a repellent property with respect to at least one active electrode material. The at least one first layer and the at least one second layer may be situated directly adjacent to one another. Also described is an energy store including the separator.
Owner:ROBERT BOSCH GMBH
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