The invention discloses a preparation method of an
electrolyte of an all-
solid-state
lithium battery. According to the invention, ball-milling mixing is combined with a low-temperature
solid-
phase reaction to realize the method; meanwhile, the amorphous
lithium-rich anti-
perovskite solid electrolyte material is prepared by means of mechanical ball milling, melting and cold
quenching and the like;the prepared amorphous
powder material is uniformly deposited on a selected substrate through
spin coating, dipping-pulling or
thermal spraying to obtain a thickness-controllable thin film, so that
lithium ion conductivity test,
activation energy measurement and total battery
assembly can be carried out; lattice constants and anti-
perovskite structure factors are regulated and controlled by dopingother
halogen atoms, so that the material is more suitable for lithium
ion migration; and non-stoichiometric phases are generated by volatilizing halides to construct lithium
ion migration channels and shelf structures. A large number of 3D fast ion transmission channels are constructed in anti-
perovskite crystal lattices through multiple means, the purpose of improving the lithium ion
conductivity of the
electrolyte material is achieved, and therefore the durability of the all-solid-state
lithium battery is improved.