The invention belongs to the technical field of
negative temperature coefficient thermistors, and in particular relates to an in-situ-generated layered composite
negative temperature coefficient thermosensitive
ceramic material, a preparation method and an application thereof. The structure of the heat-sensitive
ceramic material is a base layer, a
transition layer, and a sensitive layer in sequence, wherein: the base layer is composed of a
perovskite phase or a doped
perovskite phase, and the sensitive layer is composed of a sharp
Crystal phase or doped
spinel phase, the composition of the
transition layer is:
perovskite phase or doped perovskite phase and
spinel phase or doped
spinel mixed in equal volumes mixture. Introducing the cold spraying technology into the preparation of
layered structure composite heat-sensitive ceramics, the in-situ generation of layered composite
negative temperature coefficient heat-sensitive
ceramic materials was prepared, which overcomes the shortcomings of traditional methods and realizes the sensitivity to the thickness of the sensitive layer and the
microstructure of the material. The effective control of NTC is of great significance for the preparation of NTC thermosensitive
ceramic materials with
low resistance, high B value and high stability for suppressing surge current.