The invention relates to the technical field of monatomic
catalysis, in particular to a carbon-supported
metal monatomic catalyst prepared based on
cyclodextrin supramolecular chemistry in a controllable mode and a preparation method and application thereof.The carbon-supported
metal monatomic catalyst comprises
heteroatom-
doped carbon serving as a carrier and
metal monatomic anchored by the
heteroatom-
doped carbon, and the metal monatomic comprises Mo, Co, Ni, Fe, Pt, Ir, Au, Cu, Ru, Rh and Pd. According to the preparation method,
cyclodextrin supermolecules are taken as a
carbon source, a metal precursor is included in cavities of the
cyclodextrin supermolecules by utilizing confinement and self-
assembly effects of the cyclodextrin supermolecules, meanwhile, the cyclodextrin supermolecules and guest molecules containing heteroatoms are subjected to self-
assembly, and the carbon-supported metal monatomic catalyst is prepared through high-temperature
pyrolysis. The supramolecular self-
assembly confinement
pyrolysis method adopted by the invention is simple in preparation method, free of metal loss, free of
pollution emission, green in synthesis and high in metal monatomic loading capacity.