The invention discloses a
triazine derivative-based separator for a
vanadium battery and a preparation method of the separator. The preparation method comprises the steps of firstly, adding 2,4-diamino-6-phenyl-1,3,5-
triazine and 2-chloroethyl
vinyl ether into an
organic solvent, performing uniform mixing, performing stirring and
backflow reaction for 6-8 hours under 30-40 DEG C, performing rotaryevaporation under 40-50 DEG C to remove a
solvent, sequentially washing the product with ethyl
ether and
ethyl acetate for 3-5 times, performing rotary
evaporation under 40-50 DEG C to remove the
solvent so as to prepare a
polymerization triazine derivative; and mixing the
polymerization triazine derivative, a
polymerization monomer, heptafluoropropyl trifluorovinyl
ether, an emulsifier and a light initiator, dropping the mixture onto a glass plate, placing the glass plate under
ultraviolet light of 200-250 nanometers in
nitrogen or
inert gas
atmosphere for
irradiation for 45-55 minutes, andgenerating polymerization reaction to obtain a
polymer membrane. The preparation method is simple and practical, the separator is more excellent in
mechanical property,
ultraviolet aging resistance and
chemical stability, higher in
ion conductivity, better in
vanadium resistance, and is green and environmental-friendly, and no toxic
raw material is used during the preparation process.