Modified polytetrafluoroethylene, preparation method of modified polytetrafluoroethylene and application of modified polytetrafluoroethylene to high frequency connector
A technology of polytetrafluoroethylene and tetrafluoroethylene, which is applied in the field of preparation and composite materials, can solve problems such as high crystallinity and melt viscosity, excessive material waste, and difficult molding, and achieve good mechanical toughness
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Embodiment 1
[0032] Add 6.5g of ammonium persulfate as an initiator and 623.2g of methanol as a transfer agent in a stainless steel autoclave with a stirring device with a volume of 6000cc. Close the reaction kettle, fill the kettle with tetrafluoroethylene repeatedly to exhaust the air, then inject 3450ml of deionized water and 75g of perfluoropropyl vinyl ether, then heat to 70°C, and then fill the kettle with tetrafluoroethylene The pressure was 2.6Mpa, and tetrafluoroethylene was added during the reaction to keep the pressure constant, the stirring rate was 130rpm, and the reaction was stopped after 20 minutes.
[0033] The performance parameters of the prepared modified PTFE are shown in Table 1.
[0034] Table 1. Performance parameters of modified PTFE
[0035] project unit value density g / cm 3 2.15—2.4 Water absorption (24H) % <0.05 Tensile Strength MPa 22.5—28 Bending strength MPa 12—16 compressive strength MPa 8 Impact st...
Embodiment 2
[0038] Add 8.6g of ammonium persulfate as an initiator and 866.2g of methanol as a transfer agent in a stainless steel autoclave with a stirring device with a volume of 6000cc. Close the reaction kettle, fill the kettle with tetrafluoroethylene repeatedly to exhaust the air, then inject 3450ml of deionized water and 86.2g of perfluoropropyl vinyl ether, then heat to 70°C, and then fill the kettle with tetrafluoroethylene The internal pressure was 2.6Mpa, and tetrafluoroethylene was added during the reaction to keep the pressure constant, the stirring rate was 130rpm, and the reaction was stopped after 20 minutes.
Embodiment 3
[0040] Add 5.5g of ammonium persulfate as an initiator and 352.4g of methanol as a transfer agent in a stainless steel autoclave with a stirring device with a volume of 6000cc. Close the reaction kettle, fill the kettle with tetrafluoroethylene repeatedly to exhaust the air, then inject 3450ml of deionized water and 69g of perfluoropropyl vinyl ether, then heat to 70°C, and then fill the kettle with tetrafluoroethylene The pressure was 2.6Mpa, and tetrafluoroethylene was added during the reaction to keep the pressure constant, the stirring rate was 130rpm, and the reaction was stopped after 20 minutes.
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