30 results about "Benzanthrone" patented technology

The invention provides a method for manufacturing vat brown RP dyestuffs. The method includes that 3,9-dibromo-benzanthrone and 1-amino-anthraquinone are subjected to condensation reaction under the effects of acid-binding agents and catalysts to generate condensate brown RP imine, then ring forming agents are added into the condensate brown RP imine, and the condensate brown RP imine and the ring forming agents are subjected to ring-closure reaction and are refined to obtain vat brown RP products. The method is characterized in that the ring forming agents for the ring-closure reaction are aluminum trichloride and pyridine, and sulfuric acid and sodium chlorate are oxidized to remove copper during refining. The method has the advantages that ring-closure reaction can be completely carried out, the product yield can be increased, the cost can be reduced, and the obtained products are high in quality; impurities such as the ring forming agents and the copper can be removed by the aid of an oxidization copper removing process, the products are high in purity, and the performance of the dyestuffs can be improved.

The invention discloses a preparation method of an alkoxy benzanthrone photoinitiator, relates to the technical field of photocuring synthesis, and is provided to solve the problems that existing photoinitiators have poor compatibility with polyethylene or polypropylene, leading to insufficient tensile strength of crosslinked materials. The preparation method comprises the steps as follows: (1) mixing and stirring 3-bromobenzanthrone, alkyl alcohol and inorganic base, and then, stirring and mixing the obtained mixture with dichloromethane and water; and (2) carrying out recrystallization to prepare alkoxy benzanthrone. The invention further provides the alkoxy benzanthrone photoinitiator prepared by the method and application of the alkoxy benzanthrone photoinitiator. The alkoxy benzanthrone photoinitiator has the beneficial effects as follows: the alkoxy benzanthrone prepared by the method is used as the photoinitiator, an alkoxy structure is embedded in the structure to improve the molecular weight and solubility property of the photoinitiator, so that the photoinitiator has high crosslinking efficiency with a copolymer, and a material has good tensile strength and excellent mechanical properties and heat resistance.

The invention discloses a reducing olive T dye synthesizing novel technique. The technique comprises the following steps: firstly, 3, 9-dibromo benzanthrone, 1-aminoanthraquinone, calcined soda and copper oxides are placed into a solid-phase condensation device; after mixing, dehydration, temperature rise, heat preservation, condensation reaction and crushing, condensation compound T imine is obtained; secondly, the ring-closure reaction of the condensation compound T imine is generated in a ring-formed medium and then a reducing olive T filter mass is obtained after dilution, oxidation, waterscrubbing in a filter and blowing; thirdly, after remixing, sand grinding, standardization and drying of raw dye through addition agent, a commodity is prepared, wherein, the ring-closure reaction isto use reducing deep-blue BO raw dye mother solution after evaporation and concentration as ring forming agent and to perform ring forming reaction with the imine. The reducing olive T dye synthesizing novel technique has the advantages that: the reducing deep-blue BO mother solution which is produced by the company is recycled and used for ring closure of the reducing olive T, thereby not only greatly reducing the production cost of the raw dye and improving the product quality but also reducing pollution and emission of the three wastes. Moreover, the olive T imine also can be cycled and concentrated for use after passing through filter mass washing mother solution after ring closure.

The invention discloses a new 1-azabenzanthrone-platinum (II) complex, i.e., monochloro.mono(dimethyl sulfoxide).mono(1-azabenzanthrone) platinum (II), as well as a synthesis method and an application thereof. The complex is prepared through the following steps: weighing equivalent amounts of 1-azabenzanthrone and dichloro-di(dimethyl sulfoxide) platinum (II); dissolving in a polar solvent; heating or performing reflux reaction to obtain a target product, wherein the synthesis can specifically be performed through a solution method or a solvothermal method. Investigation shows that the complex has anti-proliferative activity on human tumor cell strains such as HepG2, SK-OV-3, SK-OV-3 / DDP, BEL-7404, T-24 and HL-7702; the result shows that the complex has obvious in-vitro anti-tumor activity, has higher potential medicinal value and is expected to be used for preparing various anti-tumor medicaments. The chemical structural formula of the complex is shown in the specification.

The invention relates to a perylene diimide fluorescent dye with ortho-substituted benzoanthrone, which uses 3,4,9,10-perylenetetracarboximide as the core group, and the acyl diimide at both ends of the core group 7-tridecyl groups are connected to the imine nitrogen atoms, and benzanthrone is connected to the ortho position of the core group. In the present invention, a 7-tridecyl group is introduced into the perylene diimide group and a benzanthrone group is introduced into the ortho position, and the obtained perylene diimide fluorescent dye of the ortho position substituted benzanthrone has a large bis The photon absorption cross section greatly improves the third-order nonlinear optical activity, and can be applied to third-order nonlinear optical materials. Simultaneously, regardless of using single-photon or two-photon to excite the aggregated state of the two, the perylene diimide fluorescent dye of the ortho-substituted benzoanthrone of the present invention exhibits AIE properties, and can be used in two-photon fluorescence imaging and two-photon dynamics Therapeutic aspects will have great application potential.

The present invention discloses a textile material with far -infrared absorption function, including: weight counts according to weights, including 25 ~ 65 copies of carbon nanoma, 12 ~ 32 copies of pyrine, pyrimidine thick ring10 ~ 15 copies of hydrocarbons, 14 ~ 30 cubes of sournium, 10 ~ 20 parts of Nahong, and 22 ~ 36 subsidiaries include infections, oxidants, and dispersion.Through the above methods, the textile materials that have a long -infrared absorption function have a good absorption performance for infrared rays. They can be suitable for the printing and dyeing of infrared camouflage clothing, reducing the probability of human targets, and improving the safety of field detection.

The invention discloses a 3-substituent benzanthrone liquid crystal dye, as well as a preparation method and application thereof. According to the preparation method, different acetenyl groups are introduced to the 3-bit of 3-bromobenzanthracen serving as a parent to improve the solubility of a molecule in a liquid crystal and reinforce the linear structure of the molecule, so that the dichroism of a liquid crystal compound can be improved; and highly delocalized electron and parent on a benzene ring are utilized to form a large conjugated system. The synthesized benzanthrone fluorescent bidirectional liquid crystal dye has a maximum absorption wavelength concentrated in a visible region and a transmission wavelength concentrated at about 500nm, and has the advantages of novel structure, easily available raw materials and simple synthesis method; and the dye has a better dichroic ratio and orderly parameters in the liquid crystal, can be used for manufacturing liquid crystal display products, and especially has high dichroism in guest-host liquid crystal displays.

The invention discloses a method for producing benzanthrone by using a primary battery technology, and belongs to the field of fine chemical engineering. The reaction is carried out in a galvanic cell device consisting of a cathode tank, an anode tank and a permeable membrane. Concentrated sulfuric acid with the same concentration is added into a cathode tank and an anode tank to serve as a reaction medium, an aluminum plate serves as an anode, stainless steel 316L serves as a cathode, anthraquinone and glycerin are added into the cathode tank, reduction and cyclization reactions are carried out in the cathode tank, the anode and the cathode are directly connected through a wire, current is generated in the reaction process, and electrons flow to the cathode from the anode through a connecting wire. And the anode tank simultaneously generates aluminum sulfate. Compared with the prior art, according to the production method of the benzanthrone, a metal reducing agent is not added in the main reactor, pollution of metal ions is avoided, aluminum sulfate generated by an anode can be conveniently and completely recycled, secondary utilization value is achieved, meanwhile, the raw material utilization rate is high, and mother liquor sulfuric acid does not contain metal salt and can be concentrated and recycled.

The invention provides a method for manufacturing vat brown RP dyestuffs. The method includes that 3,9-dibromo-benzanthrone and 1-amino-anthraquinone are subjected to condensation reaction under the effects of acid-binding agents and catalysts to generate condensate brown RP imine, then ring forming agents are added into the condensate brown RP imine, and the condensate brown RP imine and the ring forming agents are subjected to ring-closure reaction and are refined to obtain vat brown RP products. The method is characterized in that the ring forming agents for the ring-closure reaction are aluminum trichloride and pyridine, and sulfuric acid and sodium chlorate are oxidized to remove copper during refining. The method has the advantages that ring-closure reaction can be completely carried out, the product yield can be increased, the cost can be reduced, and the obtained products are high in quality; impurities such as the ring forming agents and the copper can be removed by the aid of an oxidization copper removing process, the products are high in purity, and the performance of the dyestuffs can be improved.

The invention discloses a benzanthrone derivative and a preparation method thereof. The general formula is shown as a formula I or IV, formula I or IV, R1, R2, R3 is independently selected from hydrogen, halogen, an ester group, an acyl group, a branched-chain or straight-chain C1-C20 alkyl group, a straight-chain or branched-chain C1-C20 alkoxy group, a branched-chain or straight-chain perfluoroC1-C20 alkyl group, a branched-chain or straight-chain perfluoroC1-C20 alkoxy group, a substituted or unsubstituted C4-C40 aryl group, and a substituted or unsubstituted C4-C40 heteroaryl group. The benzanthrone derivative with a novel structure provided by the invention is simple in preparation method, non-toxic and harmless, has yellow fluorescence, can be used as a potential organic functional material, and is an important dye intermediate.

The invention discloses a 9-amino oxidized isoaporphine-platinum (II) complex, a synthetic method and an application thereof. The 9-amino oxidized isoaporphine-platinum (II) complex is prepared with 9-amino oxidized isoaporphine and dichloro bis(dimethyl sulfoxide)platinum (II) as raw materials through a coordination reaction in a polar solvent. A research result shows that the inhibition effect of the complex on telomerase reaches 56.97% and is improved significantly than those of a 1-aza-benzanthrone platinum (II) complex and 6-hydroxy oxidized isoaporphine-platinum (II) complex. The complex has significant inhibition effect on the activity of the telomerase and has excellent selectivity and significant in-vitro antitumor activity on various human tumor cell strains and a normal liver cell strain. The structure formula of the complex is represented as the formula (I).