The invention discloses a synthesis process of 1,4-diamino-2-
anthraquinone sulfonate, belonging to the field of
organic synthesis. The process comprises the steps of adding a 1,4-diamino-anthraquinoneoxysome and o-
dichlorobenzene into a container, dropwise adding
chlorosulfonic acid while holding the temperature at 30-50 DEG C, heating to 140+ / -3 DEG C, holding the temperature for 6+ / -1 hours, cooling to 60-80 DEG C, transferring to water containing
sodium carbonate, stirring for a period of time, adjusting the pH to 7.5+ / -0.1, steam distilling the
solvent, cooling to 80+ / -5 DEG C, adjustingthe pH to 1+ / -0.2 with
sulfuric acid so as to separate out 1,4-diamino-2-
anthraquinone sulfonate, and filtering, so as to obtain the 1,4-diamino-2-
anthraquinone sulfonate product. The use amount of
chlorosulfonic acid in the process is one third of that of an original process, and the amount of byproduct
hydrochloric acid is one third of that of the original process, and no
sulfur dioxide gas is produced.