The invention discloses a method for preparing 1,1,1,2,3-
pentafluoropropane by using 1,1,1,2,3-pentafluoropropene. The method relates to the following steps that (1)
inert fillers and hydrogenation catalysts with different proportions are separately filled into a reactor from bottom to top, the
raw material stream flow flows from bottom to top, the proportion of the
inert fillers and the hydrogenation catalysts is kept to be gradually reduced along the direction of the
material flow, and a heat-exchange fixed-
bed reactor is filled in the way; (2) 1,1,1,2,3-pentafluoropropene is mixed and preheated with
hydrogen gas, and the obtained mixture enters the heat-exchange fixed-
bed reactor from the lower end of the heat-exchange type fixed-
bed reactor, and a gas-phase
catalytic hydrogenation reaction is performed at a temperature of 50-250 DEG C, and the generated 1,1,1,2,3-
pentafluoropropane is discharged from the upper end of the heat-exchange fixed-bed reactor; and (3) heat exchange is performed on the heat generated by the reactor by using a
cooling medium. The method has the advantages that the
hydrogenation reaction speed and the temperature rise of the catalyst bed layer are bettercontrolled, the deactivation speed of the catalysts is slowed down, and the operation period of the catalysts is prolonged.