561results about How to "Shorten crystallization time" patented technology

A phase change memory device includes a lower electrode and a porous dielectric layer having fine pores on the lower electrode. A phase change layer is provided in the fine pores of the porous dielectric layer. An upper electrode is provided on the phase change layer. Related manufacturing methods are also described.

A composite molecular sieve with TON and MFI structures is prepared in static crystallizing condition. In the procedure of preparing gel, less crystal seeds and salt are added. The Si / Al ratio on its crystal lattice is greater than 50.

A phase change memory device includes a lower electrode and a porous dielectric layer having fine pores on the lower electrode. A phase change layer is provided in the fine pores of the porous dielectric layer. An upper electrode is provided on the phase change layer. Related manufacturing methods are also described.

In thin film transistors (TFTs) having an active layer of crystalline silicon adapted for mass production, a catalytic element is introduced into doped regions of an amorphous silicon film by ion implantation or other means. This film is crystallized at a temperature below the strain point of the glass substrate. Further, a gate insulating film and a gate electrode are formed. Impurities are introduced by a self-aligning process. Then, the laminate is annealed below the strain point of the substrate to activate the dopant impurities. On the other hand, Neckel or other element is also used as a catalytic element for promoting crystallization of an amorphous silicon film. First, this catalytic element is applied in contact with the surface of the amorphous silicon film. The film is heated at 450 to 650° C. to create crystal nuclei. The film is further heated at a higher temperature to grow the crystal grains. In this way, a crystalline silicon film having improved crystallinity is formed.

The invention relates to a method for preparing no-binding agent ZSM-11 zeolite, which mainly aims at overcoming the defects of difficult recovery, easy deactivation and easy aggregation existing in the practical application of the zeolite powder and the problems of small effective surface area and limited diffusion due to the addition of the binding agent in the forming process. In the invention, at least one of diatomaceous earth, carbon white, silicasol or water glass is taken as a silicon source, at least one of aluminum oxide, aluminum salt or aluminate is taken as an aluminum source, and proper quantity of necessary crystal seed guiding agents are added and subjected to pugging, extrusion and forming so as to obtain a precursor mixture with the mass ratio of XNa2O:YAl2O3:100SiO2, wherein x is between 0.5 and 14, and y is between 0 and 6, and the precursor mixture is subjected to hydrothermal crystallization treatment in the water solution containing tetrabutyl ammonium positive ions and converted to the no-binding agent ZSM-11 zeolite. The technical proposal of the invention better resolves the problems, and can be applied to the industrial preparation of the ZSM-11 zeolite molecular sieve catalyst.

The invention provides a method of synthesizing IM-5 molecular sieve by using a composite template. The method comprises the following steps: (1) dissolving an inorganic base, an aluminum source and two templates in deionized water and carrying out uniform mixing so as to prepare a mixed solution; (2) adding a silicon source into the mixed solution obtained in step (1), optionally adding an additive and carrying out uniform mixing so as to prepare colloid or a solid-liquid mixture; (3) transferring the colloid or the solid-liquid mixture obtained in step (2) to a crystallization kettle, carrying out hydrothermal crystallization at a temperature of 120 to 200 DEG C for 1 to 10 d, carrying out cooling after crystallization and rinsing, filtering and drying the obtained mixed liquor so as to obtain raw powder of the IM-5 molecular sieve. A mole ratio of reactants satisfies the equation of SiO2: Al2O3: M2O: R1: R2: H2O = 60: 0.4-6: 6-21: 0.6-18: 0.6-12: 300-1800, wherein M2O is an alkali metal oxide, R1 is a first template, and R2 is a second template. The method provided in the invention widens the range of mixing ratios of raw materials, improves yield of a single kettle and enables time for crystallization to be further shortened and enlarged production to be easier.

The invention discloses a preparation method for mordenite with a high Si / Al ratio and a small crystal particle, which comprises the following steps of: firstly, dissolving an Al source in sodium oxide solution; after an Si source is added, stirring and dispersing for certain time at room temperature and under strong magnetic force; mixing the Al source solution and the Si source solution which are evenly dispersed into glue at the room temperature; adding inorganic lamellar precursors, such as lamellar zeolite molecular sieves, lamellar silicate and the like to serve as seed crystal; after mixture is stirred and mixed evenly at the room temperature and under the strong magnetic force, transferring into a reaction crystallization kettle; at the temperature of 150-170DEG C, carrying out crystallization reaction for 0.5-3 days; and obtaining a solid product after common suction filtration, washing and drying. The synthesis method disclosed by the invention has the characteristics that expensive organic amine template is not used as structure-directing agent, and instead, the easily-obtained inorganic lamellar precursors with abundant source and low price are used as the seed crystal to directly synthesize a mordenite molecular sieve with the high Si / Al ratio. The prepared nanometer mordenite molecular sieve has the advantages of high degree of crystallinity and purity, controllable particle size and morphology, low cost and small environment pollution, and is convenient for industrially producing on a large scale.

The invention provides a synthesis method of an IM-5 molecular sieve. The method comprises the steps of: (1) under a stirring condition, contacting an aluminum source-containing mixed solution with a silicon source to make a colloid, with the aluminum source-containing mixed solution being an aqueous solution containing inorganic alkali, a mineralizer, an aluminum source and a template agent; and (2) under crystallization reaction conditions, subjecting the colloid to hydrothermal crystallization. According to the composition of the colloid, the mole ratio of the inorganic alkali, the mineralizer, the aluminum source, the template agent, the silicon source and water satisfies the following formula: SiO2:Al2O3:M2O:MX:SDA:H2O=10:(0.1-1):(1-10):(0.1-5):(0.1-4):(50-500). The silicon source is SiO2, the aluminum source is Al2O3, the inorganic alkali is M2O, MX is the mineralizer, and SDA is the template agent. The mineralizer is a metal halide able to regulate the molecular sieve crystal growth. The method can be used for preparing the IM-5 molecular sieve with enhanced crystallinity.

The invention relates to a method for synthesizing fly ash zeolite by an alkali fusion-microwave process, particularly a method for synthesizing zeolite by utilizing industrial solid waste fly ash. In the invention, fly ash is used as a main raw material, NaOH is used as an activating agent, and an alkali fusion-microwave process is used for preparing the zeolite product. In the method, an ultrasonic dispersion process enables the activating agent to sufficiently contact the fly ash, and calcination enables the fusion reaction of the fly ash and the activating agent at high temperature, thereby increasing the conversion rate of the zeolite; the introduction of the 4A zeolite can enhance the purity of the 4A fly ash zeolite and reduce the generation of impure crystals; and microwaves are used for heating in the crystallization process, thereby greatly shortening the crystallization time of the zeolite. The method is simple to operate, has the advantages of simple equipment, short reaction time and energy saving, is convenient, feasible and practical, is suitable for industrial production of synthetic zeolite from fly ash, and develops a new way for comprehensive and cyclic utilization of fly ash.

The present invention is a meltblown fiber and a fabric manufactured from the fiber comprising reactor grade polypropylene having a melt flow rate of from 100 to 5000 and having less than 50 stereo defects per 1000 units. Further, the polypropylene is typically produced from a metallocene catalyzed process, the metallocene being at least one bridged 2,4 di-substituted indenyl metallocene in one embodiment, and a bridged 4-phenyl indenyl metallocene in another embodiment. The metallocene is part of a system that can include a fluorided support and a non-coordinating anion activator.

The invention relates to a preparation method of a ZSM-11 molecular sieve. The method comprises steps of: using an EU-1 molecular sieve as a seed; adding an EU-1 molecular sieve powder into a solution containing sodium hydroxide and a template; stirring uniformly and adding a silicon source to obtain a reaction mixture gel system, wherein a molar ratio of other components needed to be added into the reaction mixture gel system for per 100g of EU-1 molecular sieve seed is as below: 0-0.5 Na2O:0.8-5.0 SiO2:0.1-0.5 (TBA)2O:100(g)EU-1:20-110 H2O; crystallizing the reaction mixture gel under an enclosed condition at 120-180 DEG C for 36-72 h to obtain the ZSM-11 molecular sieve. Compared with a prior art, the invention has shortened crystallization time and reduced synthesis cost.

The invention discloses a super-hydrophobic polypropylene film and a preparation method thereof. The method comprises the following steps: firstly, weighing a definite amount of isotactic polypropylene granules and adding the granules into dimethyl benzene, rising the temperature to 130 DEG C, and stirring the solution by magnetic force to form 1 to 50mg / mL polypropylene solution; secondly, adding 20 to 60 percent of acetone by the volume of the solution into the polypropylene solution, and quickly stirring the solution; and finally, coating the polypropylene solution added with the acetone on a substrate by adopting a coating method, and drying the substrate for 3 to 12 hours at a temperature of between 20 and 70 DEG C to obtain a white film, namely the super-hydrophobic polypropylene film. The method has the advantages of simple operation, low cost and good controllability, does not need complex chemical treatment or expensive equipment, and is easy for industrialization. The obtained super-hydrophobic polypropylene film has the characteristics of better surface structure stability, weather-proof durability, chemical corrosion resistance and the like.

A method for producing a transparent conductive film including a transparent film substrate and a crystalline transparent conductive layer, including: a first depositing a first indium-based complex oxide having a first tetravalent metal element oxide on the transparent film substrate; and a second depositing indium oxide or a second indium-based complex oxide and lower than the tetravalent metal element oxide content of the indium-based complex oxide used in the first depositing by sputtering to form an amorphous transparent conductive layer, and crystallizing the amorphous transparent conductive layer. The method allows a reduction in crystallization time.