The invention relates to a preparation method of a molecular sieve, aiming at providing a method for synthesizing a silicon substrate molecular sieve by using a copper amine complex as a template agent. The method comprises the steps of dissolving sodium metaaluminate in deionized water, adding cupric salt, dropping organic amine in the solution after stirring, stirring completely, adding sodium hydroxide solid and stirring, then adding a silica solution in the solution, stirring for 2 to 3 hours, placing in a reaction kettle, crystallizing for 3 to 20 days at 140-180 DEG C, completely washing the reaction output with deionized water after reaction, drying for 12 hours above at 80 DEG C, exchanging through ammonium nitrate and calcining for four hours at 500 DEG C, removing the template agent to obtain the final product. Compared with the CHA molecular sieve synthesized without templates, the CHA molecular sieve has higher silica alumina ratio, stability and specific surface area and has higher reaction activity in the MTO catalytic reaction. The synthesizing method has simple template agent and lower cost, and the method for removing the template is simple and easy.