The invention belongs to the technical field of
tin metallurgy, in particular relates to a novel method for
roasting a
tin-containing high-
arsenic and high-
sulfur material by fluidized rich
oxygen. The method comprises the following steps of: mixing
oxygen into a charged gas of a fluidized furnace; controlling the
oxygen quantity to reach 22-45 wt% of the total charged gas; carrying out oxygen-enriched fluidized
roasting on the material at 600-1000 DEG C; and adding the oxygen in such a way that the quantity of the charged air is gradually reduced and the oxygen quantity is gradually increased so that the total charged gas is invariable and the oxygen concentration satisfies the process parameters while a charging
system is started for charging. According to the invention, the
arsenic and
sulfur removing rate can be effectively increased, the
roasting quality can be improved, the
smoke gas quantity generated by treatment of the unit material can be reduced, the heat loss can be reduced, the heat
utilization rate can be increased, the furnace
hearth capacity can be improved without increasing the area of the furnace
hearth, the treatment quantity can be increased and the production efficiency can be enhanced; meanwhile, the concentration of SO2 in the
smoke gas can be increased so that the problems of low SO2 concentration in the
tail gas, unfavorable acid making and environment
pollution can be solved to change the harm into the treasure in the
tail gas acid making.