The invention discloses an organic electroluminescent device comprising a first electrode, a second electrode and a layer of or a plurality of layers of organic layers located between the first electrode and the second electrode. The organic layer at least comprises a luminescent layer and an electronic transmission layer; the electronic transmission layer is 5-100 nm in thickness, and the electronic transmission layer contains at least one compound represented by the formula (I), wherein L1 and L2 are independently selected from chemical bonds, C6-C12 arylene or sub-polycyclic aromatic groups, and C3-C12 heteroarylene or sub-polyheterocyclic aromatic groups respectively; R1, R2, R3, R4 and R5 are independently selected from hydrogen, halogen, cyano groups, nitro groups, C1-C10 alkylene, C6-C30 substituted or non-substituted aryl or polycyclic aromatic groups, and C3-C30 substituted or non-substituted heteroaryl or polyheterocyclic aromatic groups respectively, and R2 and R5 can be connected with each other to form a ring structure; Ar1 and Ar2 are independently selected from C6-C30 substituted or non-substituted aryl or polycyclic aromatic groups, and C3-C30 substituted or non-substituted heteroaryl or polyheterocyclic aromatic groups respectively. The organic electroluminescent device has the advantages of low working voltage and high luminescent efficiency.