The invention relates to a
cleaner production process for synchronously extracting
vanadium and aluminum from aluminothermic
vanadium iron
slag, and belongs to the technical field of
metallurgy. The technical scheme is that: the
vanadium iron
slag is subjected to
sodium oxide roasting by using high-proportion Na2CO3 as a
roasting transforming agent, vanadium and aluminum of a clinker obtained after
sodium oxide roasting are synchronously dissolved out by using an
aqueous solution,
sodium vanadate crystals containing aluminum
hydroxide are crystallized, the purity of the obtained Al(OH)3 is over 95 percent, the purity of vanadium
pentoxide is over 98 percent, the co-extraction of the vanadium and the aluminum, the separation of the vanadium and the aluminum and the cyclic utilization of
sodium salt are realized, the
recovery rate of the vanadium is over 85 percent, the
recovery rate of the aluminum is over 60 percent, the weight of
tailings is reduced by 40 to 50 percent after leaching, and the
tailings can be used for preparing an aluminum-
magnesium flocculant by an acid method. The high-efficiency extraction of the vanadium is realized, the resource reutilization of an
aluminum element in the
slag is also realized,
wastewater discharge is avoided in the whole production process, CO2 gas for
carbonation can be replaced by roasting
flue gas, the proportion of carbon emission isreduced, and the process has remarkable economic and environmental benefits, and can be effectively applied to the treatment of the aluminothermic vanadium iron slag and related materials.