The invention discloses an acrylic structural adhesive bonded to an aluminum shell of a flame-retardant power battery, which comprises an oxidizing agent component and a reducing agent component, and the volume ratio of the oxidizing agent component and the reducing agent component is 1:1; the oxidizing agent component Including isobornyl methacrylate, 2-phenoxyethyl acrylate, 3,3,5-trimethylcycloethane methacrylate, nitrile rubber, methyl methacrylate-butyl acrylate Block copolymers, flame retardants, peroxides and stabilizers; reducing agent components include tetrahydrofurfuryl methacrylate, isooctyl methacrylate, 2‑hydroxyethyl methacrylate phosphate, terminal Carboxyl-modified neoprene, methyl methacrylate-butyl acrylate diblock copolymer, flame retardant, substituted thiourea, cobalt naphthenate, additives and stabilizers. The invention also discloses a preparation method. When the invention is in use, the heat release is low, no air holes and lines appear on the surface of the adhesive layer, and it can also play a role of flame retardancy, effectively improving the safety and reliability of the battery.