Active energy ray-curable ink and method for producing printed matter
An active energy ray, curable technology, applied in the direction of replication/marking method, ink, printing, etc., can solve the problems of reduced adhesion performance, no discovery, etc., to achieve the effect of excellent adhesion performance
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Embodiment 1~6 and comparative example 1~4
[0136] According to the mixing ratios described in Tables 1 and 2, active energy ray-curable inks that can be used for inkjet printing were produced. Specifically, MIRAMER M3130 (ethylene oxide (EO)-modified trimethylolpropane triacrylate manufactured by MIWON Corporation) and MIRAMER M240 (ethylene oxide (EO)-modified bisphenol manufactured by MIWON Corporation) were added to the container. A diacrylate), V-190 (Ethoxyethoxyethyl acrylate, manufactured by Osaka Organic Chemical Industry Co., Ltd.), IBXA (Isobornyl Acrylate, manufactured by Osaka Organic Chemical Industry Co., Ltd.), V-CAP (manufactured by ISP Corporation) N-vinyl-2-caprolactam), LIGHT ACRYLATE POA (phenoxyethyl acrylate manufactured by Kyeisha Chemical Co., Ltd.), tetrahydrofurfuryl acrylate composition containing a trace amount of tetrahydrofurfuryl alcohol, KF-54 (Shin-Etsu Chemical Industry Co., Ltd. Polysiloxane manufactured by Co., Ltd.), stirred and mixed, and then added Irgacure 819 (bis(2,4,6-trimethy...
Embodiment 7
[0178] Miramer M3130 (ethylene oxide (EO)-modified trimethylolpropane triacrylate manufactured by MIWON Corporation) and Miramer M240 (ethylene oxide manufactured by MIWON Corporation) and Alkane (EO) modified bisphenol A diacrylate), MEDOL-10 (manufactured by Osaka Organic Chemical Industry Co., Ltd., acrylic acid (2-methyl-2-ethyl-1,3-dioxolan-4-yl) ) methyl ester), IBXA (Isobornyl Acrylate manufactured by Osaka Organic Chemical Industry Co., Ltd.), V-CAP (N-vinyl-2-caprolactam manufactured by ISP Corporation), LIGHT ACRYLATE POA (Benzene Acrylate manufactured by Kyeisha Chemical Co., Ltd.) oxyethyl ester), KF-54 (polysiloxane manufactured by Shin-Etsu Chemical Co., Ltd.), and mixed with stirring, followed by adding Irgacure 819 (bis(2,4,6-trimethylbenzoyl) manufactured by BASF Corporation) -Phenylphosphine oxide), Irgacure.TPO (2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide, manufactured by BASF), Kayacure DETX-S (diethylthiazide, manufactured by Nippon Kayaku Co., Ltd. x...
Embodiment 8
[0181] The usage amount of MEDOL-10 (manufactured by Osaka Organic Chemical Industry Co., Ltd., (2-methyl-2-ethyl-1,3-dioxolan-4-yl)methyl acrylate) was changed from 20 parts by mass to Active energy was obtained by the same method as in Example 7, except that the amount of POA (phenoxyethyl acrylate manufactured by Kyōeisha Chemical Co., Ltd.) was changed from 16.3 parts by mass to 9.3 parts by mass. Radiation curable ink (C8).
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