The invention discloses a self-crosslinking
silicon-
boron-containing
high polymer matrix
ablation-resistant heat insulation material and a preparation method, and belongs to the field of high polymercomposite materials. The material comprises, by weight, 100 parts of heat-vulcanized
silicone rubber, 10-30 parts of polyborosiloxane prepolymers, 10-30 parts of white
carbon black, 5-10 parts of fibers, 10-20 parts of light
ablation-resistant fillers, 3-5 parts of vulcanizing agents and 1-3 parts of hydroxyl
silicone oil. The method includes the steps: mixing the polyborosiloxane prepolymers andthe light
ablation-resistant fillers; sequentially adding all materials to a mixer and performing plasticating; vulcanizing mixed rubber materials for three times to obtain the self-crosslinking
silicon-
boron-containing
high polymer matrix ablation-resistant heat insulation material. The material serves under the condition of
oxygen enrichment and high temperature, is subjected to carbonizing andceramic reaction in a high-temperature environment, serves as a high-temperature ablation-resistant protective layer and directly bears combined action of thermochemical ablation, gas
denudation and
particle erosion, and the ablation-resistant heat insulation performance of the material is effectively improved.