The invention discloses a bismuthino molybdenum ultralow temperature sintering microwave medium ceramic material. A phase map of Bi2O3-MoO3 binary system is taken as a beginning, a single-phase compound is taken as a basis, and a series of microwave medium material which has good microwave dielectric property (the permittivity is between 10 and 45, and the Qf is between 4,000 and 25,000GHz) and can be sintered into ceramics at a low temperature of between 550 and 900 DEG C is prepared through the methods of adjusting the proportion of the binary system and substitution for equivalent and unequivalent ions. The structural formula is (1-x)[(Bi1-yAy)2O3]-x[(Mo1-zBz)O3], wherein, A is equal to La<3+>, Nd<3+>, and Sm<3+>, B is equal to W<6+>, Nb<5+>, Ta<5+>, Sb<5+>, Ti<4+>, Zr<4+>, and Sn<4+>, x is more than or equal to 0.01 and less than or equal to 1, y is more than or equal to 0 and less than or equal to 0.20, and z is more than or equal to 0 and less than or equal to 0.20.