The invention discloses a solar photocatalytic degradation device, belongs to the technical field of sewage treatment and particularly relates to a device which solves the problems that a sewage treatment device is high in energy consumption, high in price and prone to secondary pollution by using a modified photocatalyst responsive to ultraviolet visible light and taking sunlight as a light source to drive reactions to degrade pollutants. The device mainly comprises reaction tanks, hollow pipes, air ejecting pipes, an air pump, a transparent stair-shaped photocatalytic reaction chute, circular arc baffles, a water conveying pipe, a water pump, a water collecting pool and a solar cell panel. The reaction tanks are used for providing sites for homogenizing and processing sewage, the hollow pipes are used for carrying ultraviolet visible light modulator tubes, the air ejecting pipes and the air pump are used for aerating the reaction tanks, the transparent stair-shaped photocatalytic reaction chute is used for providing a photocatalytic degradation site, the circular arc baffles are used for homogenizing and slowing down a sewage solution, the water conveying pipe and the water pump are used for conveying the sewage in the water collecting pool into the reaction tanks, the water collecting pool is used for collecting degraded sewage, and the solar cell panel is used for storing electric energy. The sunlight is mainly used, and the device has the advantages of being clean, efficient, free of secondary pollution, controllable in reaction atmosphere, high in light source utilization rate and the like.