The invention discloses a preparation method of a
sodium fluoride dual-
ion battery and application of
sodium fluoride dual-
ion battery in electrochemical defluorination. The
sodium fluoride dual-
ion battery comprises a sodium ion electrochemical material, a
fluorine ion electrochemical material and
electrolyte, wherein the sodium ion electrochemical material is prepared from Na0.44MnO2, Na2FeP2O7,Na2V6O16, NaTi2(PO4)3, Na0.44[Mn1-xTix]O2 and the like; the
fluorine ion electrochemical material comprises an electrochemical material or the electrochemical material coated by a carbon material; the electrochemical material is prepared from Bi, BiF3, Pb, PbF2, piperidines inorganic matters, dipyridyl
onium salt and the like; an NaF solution is used as the
electrolyte. The
sodium fluoride dual-ion battery in the invention is high in specific capacity and good in cycle performance; meanwhile,
fluorine ions in a solution can be removed by a fluorine ion
electrode material by utilizing electrochemical fluoride ion adsorptivity during a charging-discharging process, and the
sodium fluoride dual-ion battery can be applied to treatment of
sewage containing fluoride.